{"publication":"Angewandte Chemie International Edition","language":[{"iso":"eng"}],"citation":{"short":"P. Ghosh, R. Schoch, M. Bauer, A. Jacobi von Wangelin, Angewandte Chemie International Edition 61 (2021).","bibtex":"@article{Ghosh_Schoch_Bauer_Jacobi von Wangelin_2021, title={Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis}, volume={61}, DOI={10.1002/anie.202110821}, number={1}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Ghosh, Pradip and Schoch, Roland and Bauer, Matthias and Jacobi von Wangelin, Axel}, year={2021} }","ieee":"P. Ghosh, R. Schoch, M. Bauer, and A. Jacobi von Wangelin, “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis,” Angewandte Chemie International Edition, vol. 61, no. 1, 2021, doi: 10.1002/anie.202110821.","ama":"Ghosh P, Schoch R, Bauer M, Jacobi von Wangelin A. Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis. Angewandte Chemie International Edition. 2021;61(1). doi:10.1002/anie.202110821","mla":"Ghosh, Pradip, et al. “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis.” Angewandte Chemie International Edition, vol. 61, no. 1, Wiley, 2021, doi:10.1002/anie.202110821.","chicago":"Ghosh, Pradip, Roland Schoch, Matthias Bauer, and Axel Jacobi von Wangelin. “Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis.” Angewandte Chemie International Edition 61, no. 1 (2021). https://doi.org/10.1002/anie.202110821.","apa":"Ghosh, P., Schoch, R., Bauer, M., & Jacobi von Wangelin, A. (2021). Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis. Angewandte Chemie International Edition, 61(1). https://doi.org/10.1002/anie.202110821"},"publisher":"Wiley","type":"journal_article","keyword":["General Chemistry","Catalysis"],"_id":"41000","status":"public","article_type":"original","year":"2021","user_id":"48467","title":"Selective Benzylic CH‐Borylations by Tandem Cobalt Catalysis","abstract":[{"text":"Metal-catalyzed C−H activations are environmentally and economically attractive synthetic strategies for the construction of functional molecules as they obviate the need for pre-functionalized substrates and minimize waste generation. Great challenges reside in the control of selectivities, the utilization of unbiased hydrocarbons, and the operation of atom-economical dehydrocoupling mechanisms. An especially mild borylation of benzylic CH bonds was developed with the ligand-free pre-catalyst Co[N(SiMe3)2]2 and the bench-stable and inexpensive borylation reagent B2pin2 that produces H2 as the only by-product. A full set of kinetic, spectroscopic, and preparative mechanistic studies are indicative of a tandem catalysis mechanism of CH-borylation and dehydrocoupling via molecular CoI catalysts.","lang":"eng"}],"intvolume":" 61","issue":"1","date_updated":"2023-01-31T08:05:26Z","volume":61,"department":[{"_id":"35"},{"_id":"306"}],"doi":"10.1002/anie.202110821","date_created":"2023-01-30T16:48:53Z","publication_status":"published","author":[{"first_name":"Pradip","full_name":"Ghosh, Pradip","last_name":"Ghosh"},{"orcid":"0000-0003-2061-7289","full_name":"Schoch, Roland","last_name":"Schoch","id":"48467","first_name":"Roland"},{"last_name":"Bauer","full_name":"Bauer, Matthias","id":"47241","first_name":"Matthias","orcid":"0000-0002-9294-6076"},{"first_name":"Axel","full_name":"Jacobi von Wangelin, Axel","last_name":"Jacobi von Wangelin"}],"publication_identifier":{"issn":["1433-7851","1521-3773"]}}