{"volume":40,"department":[{"_id":"35"},{"_id":"306"}],"publication_status":"published","date_created":"2023-01-30T17:00:10Z","doi":"10.1021/acs.organomet.1c00216","publication_identifier":{"issn":["0276-7333","1520-6041"]},"author":[{"last_name":"Maier","full_name":"Maier, Sarah","first_name":"Sarah"},{"first_name":"Steve P.","last_name":"Cronin","full_name":"Cronin, Steve P."},{"first_name":"Manh-Anh","full_name":"Vu Dinh, Manh-Anh","last_name":"Vu Dinh"},{"full_name":"Li, Zheng","last_name":"Li","first_name":"Zheng"},{"first_name":"Michael","full_name":"Dyballa, Michael","last_name":"Dyballa"},{"orcid":"0000-0002-3734-7011","id":"78878","first_name":"Michał","last_name":"Nowakowski","full_name":"Nowakowski, Michał"},{"orcid":"0000-0002-9294-6076","last_name":"Bauer","full_name":"Bauer, Matthias","first_name":"Matthias","id":"47241"},{"full_name":"Estes, Deven P.","last_name":"Estes","first_name":"Deven P."}],"title":"Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations","abstract":[{"text":"Platinum hydride species catalyze a number of interesting organic reactions. However, their reactions typically involve the use of high loadings of noble metal and are difficult to recycle, making them somewhat unsustainable. We have synthesized surface-immobilized Pt–H species via oxidative addition of surface OH groups to Pt(PtBu3)2 (1), a rarely used immobilization technique in surface organometallic chemistry. The hydride species thus made were characterized by infrared, magic-angle spinning nuclear magnetic resonance, and X-ray absorption spectroscopies and catalyzed both olefin isomerization and cycloisomerization of a 1,6 enyne (5) with a high selectivity and low Pt loading.","lang":"eng"}],"issue":"11","intvolume":"        40","date_updated":"2024-05-07T11:43:17Z","type":"journal_article","keyword":["Inorganic Chemistry","Organic Chemistry","Physical and Theoretical Chemistry"],"publisher":"American Chemical Society (ACS)","citation":{"short":"S. Maier, S.P. Cronin, M.-A. Vu Dinh, Z. Li, M. Dyballa, M. Nowakowski, M. Bauer, D.P. Estes, Organometallics 40 (2021) 1751–1757.","mla":"Maier, Sarah, et al. “Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations.” <i>Organometallics</i>, vol. 40, no. 11, American Chemical Society (ACS), 2021, pp. 1751–57, doi:<a href=\"https://doi.org/10.1021/acs.organomet.1c00216\">10.1021/acs.organomet.1c00216</a>.","chicago":"Maier, Sarah, Steve P. Cronin, Manh-Anh Vu Dinh, Zheng Li, Michael Dyballa, Michał Nowakowski, Matthias Bauer, and Deven P. Estes. “Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations.” <i>Organometallics</i> 40, no. 11 (2021): 1751–57. <a href=\"https://doi.org/10.1021/acs.organomet.1c00216\">https://doi.org/10.1021/acs.organomet.1c00216</a>.","bibtex":"@article{Maier_Cronin_Vu Dinh_Li_Dyballa_Nowakowski_Bauer_Estes_2021, title={Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations}, volume={40}, DOI={<a href=\"https://doi.org/10.1021/acs.organomet.1c00216\">10.1021/acs.organomet.1c00216</a>}, number={11}, journal={Organometallics}, publisher={American Chemical Society (ACS)}, author={Maier, Sarah and Cronin, Steve P. and Vu Dinh, Manh-Anh and Li, Zheng and Dyballa, Michael and Nowakowski, Michał and Bauer, Matthias and Estes, Deven P.}, year={2021}, pages={1751–1757} }","ieee":"S. Maier <i>et al.</i>, “Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations,” <i>Organometallics</i>, vol. 40, no. 11, pp. 1751–1757, 2021, doi: <a href=\"https://doi.org/10.1021/acs.organomet.1c00216\">10.1021/acs.organomet.1c00216</a>.","apa":"Maier, S., Cronin, S. P., Vu Dinh, M.-A., Li, Z., Dyballa, M., Nowakowski, M., Bauer, M., &#38; Estes, D. P. (2021). Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations. <i>Organometallics</i>, <i>40</i>(11), 1751–1757. <a href=\"https://doi.org/10.1021/acs.organomet.1c00216\">https://doi.org/10.1021/acs.organomet.1c00216</a>","ama":"Maier S, Cronin SP, Vu Dinh M-A, et al. Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations. <i>Organometallics</i>. 2021;40(11):1751-1757. doi:<a href=\"https://doi.org/10.1021/acs.organomet.1c00216\">10.1021/acs.organomet.1c00216</a>"},"article_type":"original","status":"public","_id":"41009","user_id":"48467","year":"2021","publication":"Organometallics","language":[{"iso":"eng"}],"page":"1751-1757"}