---
res:
  bibo_abstract:
  - We present the η3-coordination of the 2-phosphaethynthiolate anion in the complex
    (PN)2La(SCP) (2) [PN=N-(2-(diisopropylphosphanyl)-4-methylphenyl)-2,4,6-trimethylanilide)].
    Structural comparison with dinuclear thiocyanate-bridged (PN)2La(μ-1,3-SCN)2La(PN)2
    (3) and azide-bridged (PN)2La(μ-1,3-N3)2La(PN)2 (4) complexes indicates that the
    [SCP]− coordination mode is mainly governed by electronic, rather than steric
    factors. Quantum mechanical investigations reveal large contributions of the antibonding
    π*-orbital of the [SCP]− ligand to the LUMO of complex 2, rendering it the ideal
    precursor for the first functionalization of the [SCP]− anion. Complex 2 was therefore
    reacted with CAACs which induced a selective rearrangement of the [SCP]− ligand
    to form the first CAAC stabilized group 15–group 16 fulminate-type complexes (PN)2La{SPC(RCAAC)}
    (5 a,b, R=Ad, Me). A detailed reaction mechanism for the SCP-to-SPC isomerization
    is proposed based on DFT calculations.@eng
  bibo_authorlist:
  - foaf_Person:
      foaf_givenName: Fabian A.
      foaf_name: Watt, Fabian A.
      foaf_surname: Watt
  - foaf_Person:
      foaf_givenName: Lukas
      foaf_name: Burkhardt, Lukas
      foaf_surname: Burkhardt
  - foaf_Person:
      foaf_givenName: Roland
      foaf_name: Schoch, Roland
      foaf_surname: Schoch
      foaf_workInfoHomepage: http://www.librecat.org/personId=48467
    orcid: 0000-0003-2061-7289
  - foaf_Person:
      foaf_givenName: Stefan
      foaf_name: Mitzinger, Stefan
      foaf_surname: Mitzinger
  - foaf_Person:
      foaf_givenName: Matthias
      foaf_name: Bauer, Matthias
      foaf_surname: Bauer
      foaf_workInfoHomepage: http://www.librecat.org/personId=47241
    orcid: 0000-0002-9294-6076
  - foaf_Person:
      foaf_givenName: Florian
      foaf_name: Weigend, Florian
      foaf_surname: Weigend
  - foaf_Person:
      foaf_givenName: Jose M.
      foaf_name: Goicoechea, Jose M.
      foaf_surname: Goicoechea
  - foaf_Person:
      foaf_givenName: Frank
      foaf_name: Tambornino, Frank
      foaf_surname: Tambornino
  - foaf_Person:
      foaf_givenName: Stephan
      foaf_name: Hohloch, Stephan
      foaf_surname: Hohloch
  bibo_doi: 10.1002/anie.202100559
  bibo_issue: '17'
  bibo_volume: 60
  dct_date: 2021^xs_gYear
  dct_isPartOf:
  - http://id.crossref.org/issn/1433-7851
  - http://id.crossref.org/issn/1521-3773
  dct_language: eng
  dct_publisher: Wiley@
  dct_subject:
  - General Chemistry
  - Catalysis
  dct_title: η            <sup>3</sup>            ‐Coordination and Functionalization
    of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)**@
...