---
res:
  bibo_abstract:
  - Here we explore the electronic structure of the diiron complex [(dppf)Fe(CO)3]0/+
    [10/+; dppf = 1,1′-bis(diphenylphosphino)ferrocene] in two oxidation states by
    an advanced multitechnique experimental approach. A combination of magnetic circular
    dichroism, X-ray absorption and emission, high-frequency electron paramagnetic
    resonance (EPR), and Mössbauer spectroscopies is used to establish that oxidation
    of 10 occurs on the carbonyl iron ion, resulting in a low-spin iron(I) ion. It
    is shown that an unequivocal result is obtained by combining several methods.
    Compound 1+ displays slow spin dynamics, which is used here to study its geometric
    structure by means of pulsed EPR methods. Surprisingly, these data show an association
    of the tetrakis[3,5-bis(trifluoromethylphenyl)]borate counterion with 1+.@eng
  bibo_authorlist:
  - foaf_Person:
      foaf_givenName: Mario
      foaf_name: Winkler, Mario
      foaf_surname: Winkler
  - foaf_Person:
      foaf_givenName: Marc
      foaf_name: Schnierle, Marc
      foaf_surname: Schnierle
  - foaf_Person:
      foaf_givenName: Felix
      foaf_name: Ehrlich, Felix
      foaf_surname: Ehrlich
  - foaf_Person:
      foaf_givenName: Kim-Isabelle
      foaf_name: Mehnert, Kim-Isabelle
      foaf_surname: Mehnert
  - foaf_Person:
      foaf_givenName: David
      foaf_name: Hunger, David
      foaf_surname: Hunger
  - foaf_Person:
      foaf_givenName: Alena M.
      foaf_name: Sheveleva, Alena M.
      foaf_surname: Sheveleva
  - foaf_Person:
      foaf_givenName: Lukas
      foaf_name: Burkhardt, Lukas
      foaf_surname: Burkhardt
  - foaf_Person:
      foaf_givenName: Matthias
      foaf_name: Bauer, Matthias
      foaf_surname: Bauer
      foaf_workInfoHomepage: http://www.librecat.org/personId=47241
    orcid: 0000-0002-9294-6076
  - foaf_Person:
      foaf_givenName: Floriana
      foaf_name: Tuna, Floriana
      foaf_surname: Tuna
  - foaf_Person:
      foaf_givenName: Mark R.
      foaf_name: Ringenberg, Mark R.
      foaf_surname: Ringenberg
  - foaf_Person:
      foaf_givenName: Joris
      foaf_name: van Slageren, Joris
      foaf_surname: van Slageren
  bibo_doi: 10.1021/acs.inorgchem.0c03259
  bibo_issue: '5'
  bibo_volume: 60
  dct_date: 2021^xs_gYear
  dct_isPartOf:
  - http://id.crossref.org/issn/0020-1669
  - http://id.crossref.org/issn/1520-510X
  dct_language: eng
  dct_publisher: American Chemical Society (ACS)@
  dct_subject:
  - Inorganic Chemistry
  - Physical and Theoretical Chemistry
  dct_title: 'Electronic Structure of a Diiron Complex: A Multitechnique Experimental
    Study of [(dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>@'
...