{"language":[{"iso":"eng"}],"page":"2856-2865","publication":"Inorganic Chemistry","year":"2021","user_id":"48467","article_type":"original","_id":"41012","status":"public","publisher":"American Chemical Society (ACS)","type":"journal_article","keyword":["Inorganic Chemistry","Physical and Theoretical Chemistry"],"citation":{"ama":"Winkler M, Schnierle M, Ehrlich F, et al. Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>. <i>Inorganic Chemistry</i>. 2021;60(5):2856-2865. doi:<a href=\"https://doi.org/10.1021/acs.inorgchem.0c03259\">10.1021/acs.inorgchem.0c03259</a>","bibtex":"@article{Winkler_Schnierle_Ehrlich_Mehnert_Hunger_Sheveleva_Burkhardt_Bauer_Tuna_Ringenberg_et al._2021, title={Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>}, volume={60}, DOI={<a href=\"https://doi.org/10.1021/acs.inorgchem.0c03259\">10.1021/acs.inorgchem.0c03259</a>}, number={5}, journal={Inorganic Chemistry}, publisher={American Chemical Society (ACS)}, author={Winkler, Mario and Schnierle, Marc and Ehrlich, Felix and Mehnert, Kim-Isabelle and Hunger, David and Sheveleva, Alena M. and Burkhardt, Lukas and Bauer, Matthias and Tuna, Floriana and Ringenberg, Mark R. and et al.}, year={2021}, pages={2856–2865} }","ieee":"M. Winkler <i>et al.</i>, “Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>,” <i>Inorganic Chemistry</i>, vol. 60, no. 5, pp. 2856–2865, 2021, doi: <a href=\"https://doi.org/10.1021/acs.inorgchem.0c03259\">10.1021/acs.inorgchem.0c03259</a>.","short":"M. Winkler, M. Schnierle, F. Ehrlich, K.-I. Mehnert, D. Hunger, A.M. Sheveleva, L. Burkhardt, M. Bauer, F. Tuna, M.R. Ringenberg, J. van Slageren, Inorganic Chemistry 60 (2021) 2856–2865.","apa":"Winkler, M., Schnierle, M., Ehrlich, F., Mehnert, K.-I., Hunger, D., Sheveleva, A. M., Burkhardt, L., Bauer, M., Tuna, F., Ringenberg, M. R., &#38; van Slageren, J. (2021). Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>. <i>Inorganic Chemistry</i>, <i>60</i>(5), 2856–2865. <a href=\"https://doi.org/10.1021/acs.inorgchem.0c03259\">https://doi.org/10.1021/acs.inorgchem.0c03259</a>","mla":"Winkler, Mario, et al. “Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(Dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>.” <i>Inorganic Chemistry</i>, vol. 60, no. 5, American Chemical Society (ACS), 2021, pp. 2856–65, doi:<a href=\"https://doi.org/10.1021/acs.inorgchem.0c03259\">10.1021/acs.inorgchem.0c03259</a>.","chicago":"Winkler, Mario, Marc Schnierle, Felix Ehrlich, Kim-Isabelle Mehnert, David Hunger, Alena M. Sheveleva, Lukas Burkhardt, et al. “Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(Dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>.” <i>Inorganic Chemistry</i> 60, no. 5 (2021): 2856–65. <a href=\"https://doi.org/10.1021/acs.inorgchem.0c03259\">https://doi.org/10.1021/acs.inorgchem.0c03259</a>."},"date_updated":"2023-01-31T08:07:16Z","intvolume":"        60","issue":"5","abstract":[{"lang":"eng","text":"Here we explore the electronic structure of the diiron complex [(dppf)Fe(CO)3]0/+ [10/+; dppf = 1,1′-bis(diphenylphosphino)ferrocene] in two oxidation states by an advanced multitechnique experimental approach. A combination of magnetic circular dichroism, X-ray absorption and emission, high-frequency electron paramagnetic resonance (EPR), and Mössbauer spectroscopies is used to establish that oxidation of 10 occurs on the carbonyl iron ion, resulting in a low-spin iron(I) ion. It is shown that an unequivocal result is obtained by combining several methods. Compound 1+ displays slow spin dynamics, which is used here to study its geometric structure by means of pulsed EPR methods. Surprisingly, these data show an association of the tetrakis[3,5-bis(trifluoromethylphenyl)]borate counterion with 1+."}],"title":"Electronic Structure of a Diiron Complex: A Multitechnique Experimental Study of [(dppf)Fe(CO) <sub>3</sub>]<sup>+/0</sup>","author":[{"first_name":"Mario","full_name":"Winkler, Mario","last_name":"Winkler"},{"first_name":"Marc","full_name":"Schnierle, Marc","last_name":"Schnierle"},{"first_name":"Felix","full_name":"Ehrlich, Felix","last_name":"Ehrlich"},{"last_name":"Mehnert","full_name":"Mehnert, Kim-Isabelle","first_name":"Kim-Isabelle"},{"first_name":"David","last_name":"Hunger","full_name":"Hunger, David"},{"first_name":"Alena M.","last_name":"Sheveleva","full_name":"Sheveleva, Alena M."},{"last_name":"Burkhardt","full_name":"Burkhardt, Lukas","first_name":"Lukas"},{"first_name":"Matthias","id":"47241","last_name":"Bauer","full_name":"Bauer, Matthias","orcid":"0000-0002-9294-6076"},{"full_name":"Tuna, Floriana","last_name":"Tuna","first_name":"Floriana"},{"last_name":"Ringenberg","full_name":"Ringenberg, Mark R.","first_name":"Mark R."},{"first_name":"Joris","last_name":"van Slageren","full_name":"van Slageren, Joris"}],"publication_identifier":{"issn":["0020-1669","1520-510X"]},"date_created":"2023-01-30T17:00:49Z","doi":"10.1021/acs.inorgchem.0c03259","publication_status":"published","department":[{"_id":"35"},{"_id":"306"}],"volume":60}