Gold(ii) species catalyse the cyclisation of N(2-propyn-1-yl)benzamide to 2-phenyl-5-vinylidene-2-oxazoline without halide abstraction while the neutral gold(i) complex is inactive indicating a gold(ii/i) redox-switch.
"}],"date_created":"2023-01-30T20:01:46Z","title":"Gold(ii) in redox-switchable gold(i) catalysis","author":[{"last_name":"Veit","full_name":"Veit, Philipp","first_name":"Philipp"},{"first_name":"Carla","full_name":"Volkert, Carla","last_name":"Volkert"},{"first_name":"Christoph","last_name":"Förster","full_name":"Förster, Christoph"},{"last_name":"Ksenofontov","full_name":"Ksenofontov, Vadim","first_name":"Vadim"},{"first_name":"Steffen","last_name":"Schlicher","full_name":"Schlicher, Steffen"},{"first_name":"Matthias","id":"47241","orcid":"0000-0002-9294-6076","last_name":"Bauer","full_name":"Bauer, Matthias"},{"first_name":"Katja","full_name":"Heinze, Katja","last_name":"Heinze"}],"type":"journal_article","_id":"41050","doi":"10.1039/c9cc00283a","issue":"32","keyword":["Materials Chemistry","Metals and Alloys","Surfaces","Coatings and Films","General Chemistry","Ceramics and Composites","Electronic","Optical and Magnetic Materials","Catalysis"],"volume":55,"language":[{"iso":"eng"}],"year":"2019","page":"4615-4618","publication":"Chemical Communications","department":[{"_id":"35"},{"_id":"306"}],"status":"public","citation":{"apa":"Veit, P., Volkert, C., Förster, C., Ksenofontov, V., Schlicher, S., Bauer, M., & Heinze, K. (2019). Gold(<scp>ii</scp>) in redox-switchable gold(<scp>i</scp>) catalysis. Chemical Communications, 55(32), 4615–4618. https://doi.org/10.1039/c9cc00283a","ama":"Veit P, Volkert C, Förster C, et al. Gold(<scp>ii</scp>) in redox-switchable gold(<scp>i</scp>) catalysis. Chemical Communications. 2019;55(32):4615-4618. doi:10.1039/c9cc00283a","bibtex":"@article{Veit_Volkert_Förster_Ksenofontov_Schlicher_Bauer_Heinze_2019, title={Gold(<scp>ii</scp>) in redox-switchable gold(<scp>i</scp>) catalysis}, volume={55}, DOI={10.1039/c9cc00283a}, number={32}, journal={Chemical Communications}, publisher={Royal Society of Chemistry (RSC)}, author={Veit, Philipp and Volkert, Carla and Förster, Christoph and Ksenofontov, Vadim and Schlicher, Steffen and Bauer, Matthias and Heinze, Katja}, year={2019}, pages={4615–4618} }","ieee":"P. Veit et al., “Gold(<scp>ii</scp>) in redox-switchable gold(<scp>i</scp>) catalysis,” Chemical Communications, vol. 55, no. 32, pp. 4615–4618, 2019, doi: 10.1039/c9cc00283a.","chicago":"Veit, Philipp, Carla Volkert, Christoph Förster, Vadim Ksenofontov, Steffen Schlicher, Matthias Bauer, and Katja Heinze. “Gold(<scp>ii</Scp>) in Redox-Switchable Gold(<scp>i</Scp>) Catalysis.” Chemical Communications 55, no. 32 (2019): 4615–18. https://doi.org/10.1039/c9cc00283a.","mla":"Veit, Philipp, et al. “Gold(<scp>ii</Scp>) in Redox-Switchable Gold(<scp>i</Scp>) Catalysis.” Chemical Communications, vol. 55, no. 32, Royal Society of Chemistry (RSC), 2019, pp. 4615–18, doi:10.1039/c9cc00283a.","short":"P. Veit, C. Volkert, C. Förster, V. Ksenofontov, S. Schlicher, M. Bauer, K. Heinze, Chemical Communications 55 (2019) 4615–4618."},"publication_identifier":{"issn":["1359-7345","1364-548X"]},"publisher":"Royal Society of Chemistry (RSC)","publication_status":"published","intvolume":" 55","date_updated":"2023-01-31T08:29:37Z"}