{"extern":"1","abstract":[{"lang":"eng","text":"A series of new organic donor–π–acceptor dyes incorporating a diquat moiety as a novel electron-acceptor unit have been synthesized and characterized. The analytical data were supported by DFT calculations. These dyes were explored in the aerobic thiocyanation of indoles and pyrroles. Here they showed a high photocatalytic activity under visible light, giving isolated yields of up to 97 %. In addition, the photocatalytic activity of standalone diquat and methyl viologen through formation of an electron donor acceptor complex is presented."}],"related_material":{"link":[{"url":"https://chemistry-europe.onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fchem.202203541&file=chem202203541-sup-0001-misc_information.pdf","relation":"supplementary_material"}]},"title":"Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation","date_updated":"2023-06-26T02:29:15Z","issue":"22","department":[{"_id":"35"},{"_id":"15"},{"_id":"170"},{"_id":"295"},{"_id":"230"}],"project":[{"_id":"52","name":"PC2: Computing Resources Provided by the Paderborn Center for Parallel Computing"}],"volume":" 29","publication_identifier":{"issn":["0947-6539","1521-3765"]},"main_file_link":[{"url":"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.202203541","open_access":"1"}],"author":[{"full_name":"Meier, Armin","last_name":"Meier","first_name":"Armin"},{"full_name":"Badalov, Sabuhi","last_name":"Badalov","id":"78800","first_name":"Sabuhi","orcid":"0000-0002-8481-4161"},{"first_name":"Timur","id":"65612","last_name":"Biktagirov","full_name":"Biktagirov, Timur"},{"orcid":"0000-0002-2717-5076","id":"468","first_name":"Wolf Gero","full_name":"Schmidt, Wolf Gero","last_name":"Schmidt"},{"last_name":"Wilhelm","full_name":"Wilhelm, René","first_name":"René"}],"publication_status":"published","date_created":"2023-04-16T18:14:24Z","doi":"10.1002/chem.202203541","publication":"Chemistry – A European Journal","page":" e202203541","language":[{"iso":"eng"}],"citation":{"mla":"Meier, Armin, et al. “Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation.” <i>Chemistry – A European Journal</i>, vol. 29, no. 22, Wiley, 2023, p. e202203541, doi:<a href=\"https://doi.org/10.1002/chem.202203541\">10.1002/chem.202203541</a>.","chicago":"Meier, Armin, Sabuhi Badalov, Timur Biktagirov, Wolf Gero Schmidt, and René Wilhelm. “Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation.” <i>Chemistry – A European Journal</i> 29, no. 22 (2023): e202203541. <a href=\"https://doi.org/10.1002/chem.202203541\">https://doi.org/10.1002/chem.202203541</a>.","apa":"Meier, A., Badalov, S., Biktagirov, T., Schmidt, W. G., &#38; Wilhelm, R. (2023). Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation. <i>Chemistry – A European Journal</i>, <i>29</i>(22), e202203541. <a href=\"https://doi.org/10.1002/chem.202203541\">https://doi.org/10.1002/chem.202203541</a>","short":"A. Meier, S. Badalov, T. Biktagirov, W.G. Schmidt, R. Wilhelm, Chemistry – A European Journal 29 (2023) e202203541.","bibtex":"@article{Meier_Badalov_Biktagirov_Schmidt_Wilhelm_2023, title={Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation}, volume={29}, DOI={<a href=\"https://doi.org/10.1002/chem.202203541\">10.1002/chem.202203541</a>}, number={22}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Meier, Armin and Badalov, Sabuhi and Biktagirov, Timur and Schmidt, Wolf Gero and Wilhelm, René}, year={2023}, pages={e202203541} }","ieee":"A. Meier, S. Badalov, T. Biktagirov, W. G. Schmidt, and R. Wilhelm, “Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation,” <i>Chemistry – A European Journal</i>, vol. 29, no. 22, p. e202203541, 2023, doi: <a href=\"https://doi.org/10.1002/chem.202203541\">10.1002/chem.202203541</a>.","ama":"Meier A, Badalov S, Biktagirov T, Schmidt WG, Wilhelm R. Diquat Based Dyes: A New Class of Photoredox Catalysts and Their Use in Aerobic Thiocyanation. <i>Chemistry – A European Journal</i>. 2023;29(22):e202203541. doi:<a href=\"https://doi.org/10.1002/chem.202203541\">10.1002/chem.202203541</a>"},"keyword":["General Chemistry","Catalysis","Organic Chemistry"],"oa":"1","type":"journal_article","publisher":"Wiley","user_id":"78800","year":"2023","status":"public","_id":"43827","article_type":"original"}