Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis Kirchhof, Manuel Gugeler, Katrin Beurer, Ann-Katrin Fischer, Felix Richard Batman, Derman Bauch, Soeren M. Kolin, Sofia Nicholas, Elliot Schoch, Roland Vogler, Charlotte Kousik, Shravan R. Zens, Anna Plietker, Bernd Atanasova, Petia Naumann, Stefan Bauer, Matthias Bruckner, Johanna R. Traa, Yvonne Kästner, Johannes Laschat, Sabine Catalysis Improved enantioselectivity in the 1,2-addition was observed for chiral Rh norbornadiene catalysts immobilized on ordered mesoporous silica with small pores. Confinement effects were rationalized by experimental and computational studies. Royal Society of Chemistry (RSC) 2023 info:eu-repo/semantics/article doc-type:article text http://purl.org/coar/resource_type/c_6501 https://ris.uni-paderborn.de/record/52343 Kirchhof M, Gugeler K, Beurer A-K, et al. Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis. <i>Catalysis Science Technology</i>. 2023;13(12):3709-3724. doi:<a href="https://doi.org/10.1039/d3cy00381g">10.1039/d3cy00381g</a> eng info:eu-repo/semantics/altIdentifier/doi/10.1039/d3cy00381g info:eu-repo/semantics/altIdentifier/issn/2044-4753 info:eu-repo/semantics/altIdentifier/issn/2044-4761 info:eu-repo/semantics/closedAccess