{"abstract":[{"text":"Improved enantioselectivity in the 1,2-addition was observed for chiral Rh norbornadiene catalysts immobilized on ordered mesoporous silica with small pores. Confinement effects were rationalized by experimental and computational studies.","lang":"eng"}],"date_created":"2024-03-07T09:12:06Z","status":"public","doi":"10.1039/d3cy00381g","article_type":"original","publisher":"Royal Society of Chemistry (RSC)","title":"Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis","_id":"52343","language":[{"iso":"eng"}],"date_updated":"2025-06-16T09:00:17Z","page":"3709-3724","type":"journal_article","keyword":["Catalysis"],"volume":13,"year":"2023","user_id":"48467","author":[{"last_name":"Kirchhof","full_name":"Kirchhof, Manuel","first_name":"Manuel"},{"first_name":"Katrin","last_name":"Gugeler","full_name":"Gugeler, Katrin"},{"full_name":"Beurer, Ann-Katrin","last_name":"Beurer","first_name":"Ann-Katrin"},{"first_name":"Felix Richard","full_name":"Fischer, Felix Richard","last_name":"Fischer"},{"first_name":"Derman","last_name":"Batman","full_name":"Batman, Derman"},{"first_name":"Soeren M.","last_name":"Bauch","full_name":"Bauch, Soeren M."},{"full_name":"Kolin, Sofia","last_name":"Kolin","first_name":"Sofia"},{"first_name":"Elliot","full_name":"Nicholas, Elliot","last_name":"Nicholas"},{"id":"48467","first_name":"Roland","last_name":"Schoch","full_name":"Schoch, Roland","orcid":"0000-0003-2061-7289"},{"last_name":"Vogler","full_name":"Vogler, Charlotte","first_name":"Charlotte"},{"full_name":"Kousik, Shravan R.","last_name":"Kousik","first_name":"Shravan R."},{"full_name":"Zens, Anna","last_name":"Zens","first_name":"Anna"},{"last_name":"Plietker","full_name":"Plietker, Bernd","first_name":"Bernd"},{"first_name":"Petia","full_name":"Atanasova, Petia","last_name":"Atanasova"},{"full_name":"Naumann, Stefan","last_name":"Naumann","first_name":"Stefan"},{"full_name":"Bauer, Matthias","last_name":"Bauer","orcid":"0000-0002-9294-6076","id":"47241","first_name":"Matthias"},{"first_name":"Johanna R.","full_name":"Bruckner, Johanna R.","last_name":"Bruckner"},{"full_name":"Traa, Yvonne","last_name":"Traa","first_name":"Yvonne"},{"first_name":"Johannes","last_name":"Kästner","full_name":"Kästner, Johannes"},{"last_name":"Laschat","full_name":"Laschat, Sabine","first_name":"Sabine"}],"intvolume":"        13","issue":"12","publication":"Catalysis Science Technology","citation":{"ieee":"M. Kirchhof <i>et al.</i>, “Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis,” <i>Catalysis Science Technology</i>, vol. 13, no. 12, pp. 3709–3724, 2023, doi: <a href=\"https://doi.org/10.1039/d3cy00381g\">10.1039/d3cy00381g</a>.","apa":"Kirchhof, M., Gugeler, K., Beurer, A.-K., Fischer, F. R., Batman, D., Bauch, S. M., Kolin, S., Nicholas, E., Schoch, R., Vogler, C., Kousik, S. R., Zens, A., Plietker, B., Atanasova, P., Naumann, S., Bauer, M., Bruckner, J. R., Traa, Y., Kästner, J., &#38; Laschat, S. (2023). Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis. <i>Catalysis Science Technology</i>, <i>13</i>(12), 3709–3724. <a href=\"https://doi.org/10.1039/d3cy00381g\">https://doi.org/10.1039/d3cy00381g</a>","chicago":"Kirchhof, Manuel, Katrin Gugeler, Ann-Katrin Beurer, Felix Richard Fischer, Derman Batman, Soeren M. Bauch, Sofia Kolin, et al. “Tethering Chiral Rh Diene Complexes inside Mesoporous Solids: Experimental and Theoretical Study of Substituent, Pore and Linker Effects on Asymmetric Catalysis.” <i>Catalysis Science Technology</i> 13, no. 12 (2023): 3709–24. <a href=\"https://doi.org/10.1039/d3cy00381g\">https://doi.org/10.1039/d3cy00381g</a>.","short":"M. Kirchhof, K. Gugeler, A.-K. Beurer, F.R. Fischer, D. Batman, S.M. Bauch, S. Kolin, E. Nicholas, R. Schoch, C. Vogler, S.R. Kousik, A. Zens, B. Plietker, P. Atanasova, S. Naumann, M. Bauer, J.R. Bruckner, Y. Traa, J. Kästner, S. Laschat, Catalysis Science Technology 13 (2023) 3709–3724.","mla":"Kirchhof, Manuel, et al. “Tethering Chiral Rh Diene Complexes inside Mesoporous Solids: Experimental and Theoretical Study of Substituent, Pore and Linker Effects on Asymmetric Catalysis.” <i>Catalysis Science Technology</i>, vol. 13, no. 12, Royal Society of Chemistry (RSC), 2023, pp. 3709–24, doi:<a href=\"https://doi.org/10.1039/d3cy00381g\">10.1039/d3cy00381g</a>.","bibtex":"@article{Kirchhof_Gugeler_Beurer_Fischer_Batman_Bauch_Kolin_Nicholas_Schoch_Vogler_et al._2023, title={Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis}, volume={13}, DOI={<a href=\"https://doi.org/10.1039/d3cy00381g\">10.1039/d3cy00381g</a>}, number={12}, journal={Catalysis Science Technology}, publisher={Royal Society of Chemistry (RSC)}, author={Kirchhof, Manuel and Gugeler, Katrin and Beurer, Ann-Katrin and Fischer, Felix Richard and Batman, Derman and Bauch, Soeren M. and Kolin, Sofia and Nicholas, Elliot and Schoch, Roland and Vogler, Charlotte and et al.}, year={2023}, pages={3709–3724} }","ama":"Kirchhof M, Gugeler K, Beurer A-K, et al. Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis. <i>Catalysis Science Technology</i>. 2023;13(12):3709-3724. doi:<a href=\"https://doi.org/10.1039/d3cy00381g\">10.1039/d3cy00381g</a>"},"publication_identifier":{"issn":["2044-4753","2044-4761"]},"department":[{"_id":"306"}],"publication_status":"published"}