@article{52541,
  abstract     = {{<jats:title>Abstract</jats:title><jats:p>We conducted an investigation into the palladium‐catalyzed carbon‐sulfur cross‐coupling reaction involving a 2‐bromothiophene derivative and potassium thioacetate as a substitute for hydrogen sulfide. This investigation utilized kinetic and computational methods. We synthesized two palladium complexes supported by the bisphosphane ligands bis(diphenylphosphino)ferrocene (DPPF) and bis(diisopropylphosphino)ferrocene (D<jats:italic>i</jats:italic>PPF), as well as their tentative intermediates in the catalytic cycle. Reaction rates were measured and then compared to computational predictions.</jats:p>}},
  author       = {{Peschtrich, Sebastian and Schoch, Roland and Kuckling, Dirk and Paradies, Jan}},
  issn         = {{1434-193X}},
  journal      = {{European Journal of Organic Chemistry}},
  keywords     = {{Organic Chemistry, Physical and Theoretical Chemistry}},
  number       = {{8}},
  publisher    = {{Wiley}},
  title        = {{{A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes}}},
  doi          = {{10.1002/ejoc.202301207}},
  volume       = {{27}},
  year         = {{2024}},
}