[{"_id":"52541","publisher":"Wiley","volume":27,"user_id":"53339","status":"public","citation":{"bibtex":"@article{Peschtrich_Schoch_Kuckling_Paradies_2024, title={A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes}, volume={27}, DOI={<a href=\"https://doi.org/10.1002/ejoc.202301207\">10.1002/ejoc.202301207</a>}, number={8}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Peschtrich, Sebastian and Schoch, Roland and Kuckling, Dirk and Paradies, Jan}, year={2024} }","ama":"Peschtrich S, Schoch R, Kuckling D, Paradies J. A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes. <i>European Journal of Organic Chemistry</i>. 2024;27(8). doi:<a href=\"https://doi.org/10.1002/ejoc.202301207\">10.1002/ejoc.202301207</a>","mla":"Peschtrich, Sebastian, et al. “A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes.” <i>European Journal of Organic Chemistry</i>, vol. 27, no. 8, Wiley, 2024, doi:<a href=\"https://doi.org/10.1002/ejoc.202301207\">10.1002/ejoc.202301207</a>.","short":"S. Peschtrich, R. Schoch, D. Kuckling, J. Paradies, European Journal of Organic Chemistry 27 (2024).","chicago":"Peschtrich, Sebastian, Roland Schoch, Dirk Kuckling, and Jan Paradies. “A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes.” <i>European Journal of Organic Chemistry</i> 27, no. 8 (2024). <a href=\"https://doi.org/10.1002/ejoc.202301207\">https://doi.org/10.1002/ejoc.202301207</a>.","ieee":"S. Peschtrich, R. Schoch, D. Kuckling, and J. Paradies, “A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes,” <i>European Journal of Organic Chemistry</i>, vol. 27, no. 8, 2024, doi: <a href=\"https://doi.org/10.1002/ejoc.202301207\">10.1002/ejoc.202301207</a>.","apa":"Peschtrich, S., Schoch, R., Kuckling, D., &#38; Paradies, J. (2024). A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes. <i>European Journal of Organic Chemistry</i>, <i>27</i>(8). <a href=\"https://doi.org/10.1002/ejoc.202301207\">https://doi.org/10.1002/ejoc.202301207</a>"},"language":[{"iso":"eng"}],"doi":"10.1002/ejoc.202301207","publication_identifier":{"issn":["1434-193X","1099-0690"]},"author":[{"full_name":"Peschtrich, Sebastian","first_name":"Sebastian","last_name":"Peschtrich"},{"id":"48467","full_name":"Schoch, Roland","last_name":"Schoch","orcid":"0000-0003-2061-7289","first_name":"Roland"},{"first_name":"Dirk","last_name":"Kuckling","full_name":"Kuckling, Dirk","id":"287"},{"id":"53339","full_name":"Paradies, Jan","orcid":"0000-0002-3698-668X","first_name":"Jan","last_name":"Paradies"}],"title":"A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes","year":"2024","intvolume":"        27","date_updated":"2024-03-13T17:17:37Z","publication_status":"published","date_created":"2024-03-13T17:15:14Z","department":[{"_id":"2"},{"_id":"389"}],"keyword":["Organic Chemistry","Physical and Theoretical Chemistry"],"type":"journal_article","issue":"8","publication":"European Journal of Organic Chemistry","abstract":[{"text":"<jats:title>Abstract</jats:title><jats:p>We conducted an investigation into the palladium‐catalyzed carbon‐sulfur cross‐coupling reaction involving a 2‐bromothiophene derivative and potassium thioacetate as a substitute for hydrogen sulfide. This investigation utilized kinetic and computational methods. We synthesized two palladium complexes supported by the bisphosphane ligands bis(diphenylphosphino)ferrocene (DPPF) and bis(diisopropylphosphino)ferrocene (D<jats:italic>i</jats:italic>PPF), as well as their tentative intermediates in the catalytic cycle. Reaction rates were measured and then compared to computational predictions.</jats:p>","lang":"eng"}]}]