{"citation":{"chicago":"Krämer, Felix, Jan Paradies, Israel Fernández, and Frank Breher. “Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles.” <i>Chemistry – A European Journal</i> 30, no. 5 (2023). <a href=\"https://doi.org/10.1002/chem.202303380\">https://doi.org/10.1002/chem.202303380</a>.","mla":"Krämer, Felix, et al. “Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles.” <i>Chemistry – A European Journal</i>, vol. 30, no. 5, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/chem.202303380\">10.1002/chem.202303380</a>.","apa":"Krämer, F., Paradies, J., Fernández, I., &#38; Breher, F. (2023). Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles. <i>Chemistry – A European Journal</i>, <i>30</i>(5). <a href=\"https://doi.org/10.1002/chem.202303380\">https://doi.org/10.1002/chem.202303380</a>","short":"F. Krämer, J. Paradies, I. Fernández, F. Breher, Chemistry – A European Journal 30 (2023).","ieee":"F. Krämer, J. Paradies, I. Fernández, and F. Breher, “Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles,” <i>Chemistry – A European Journal</i>, vol. 30, no. 5, 2023, doi: <a href=\"https://doi.org/10.1002/chem.202303380\">10.1002/chem.202303380</a>.","bibtex":"@article{Krämer_Paradies_Fernández_Breher_2023, title={Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles}, volume={30}, DOI={<a href=\"https://doi.org/10.1002/chem.202303380\">10.1002/chem.202303380</a>}, number={5}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Krämer, Felix and Paradies, Jan and Fernández, Israel and Breher, Frank}, year={2023} }","ama":"Krämer F, Paradies J, Fernández I, Breher F. Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles. <i>Chemistry – A European Journal</i>. 2023;30(5). doi:<a href=\"https://doi.org/10.1002/chem.202303380\">10.1002/chem.202303380</a>"},"volume":30,"publisher":"Wiley","keyword":["General Chemistry","Catalysis","Organic Chemistry"],"type":"journal_article","department":[{"_id":"2"},{"_id":"389"}],"_id":"52542","status":"public","doi":"10.1002/chem.202303380","date_created":"2024-03-13T17:17:52Z","publication_status":"published","year":"2023","author":[{"full_name":"Krämer, Felix","last_name":"Krämer","first_name":"Felix"},{"last_name":"Paradies","full_name":"Paradies, Jan","id":"53339","first_name":"Jan","orcid":"0000-0002-3698-668X"},{"first_name":"Israel","last_name":"Fernández","full_name":"Fernández, Israel"},{"full_name":"Breher, Frank","last_name":"Breher","first_name":"Frank"}],"publication_identifier":{"issn":["0947-6539","1521-3765"]},"user_id":"53339","title":"Quo Vadis CO<sub>2</sub> Activation: Catalytic Reduction of CO<sub>2</sub> to Methanol Using Aluminum and Gallium/Carbon‐based Ambiphiles","publication":"Chemistry – A European Journal","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>We report on so‐called “hidden FLPs” (FLP: frustrated Lewis pair) consisting of a phosphorus ylide featuring a group 13 fragment in the <jats:italic>ortho</jats:italic> position of a phenyl ring scaffold to form five‐membered ring structures. Although the formation of the Lewis acid/base adducts was observed in the solid state, most of the title compounds readily react with carbon dioxide to provide stable insertion products. Strikingly, 0.3–3.0 mol% of the reported aluminum and gallium/carbon‐based ambiphiles catalyze the reduction of CO<jats:sub>2</jats:sub> to methanol with satisfactory high selectivity and yields using pinacol borane as stoichiometric reduction equivalent. Comprehensive computational studies provided valuable mechanistic insights and shed more light on activity differences.</jats:p>"}],"language":[{"iso":"eng"}],"intvolume":"        30","issue":"5","date_updated":"2024-03-13T17:18:17Z"}