{"date_updated":"2024-05-07T09:07:57Z","language":[{"iso":"eng"}],"publication":"Chemistry – A European Journal","abstract":[{"text":"Transition metal complexes, particularly copper hydrides, play an important role in various catalytic processes and molecular inorganic chemistry. This study employs synchrotron hard X‐ray spectroscopy to gain insights into the geometric and electronic properties of copper hydrides as potential catalysts for CO2 hydrogenation. The potential of high energy resolution X‐ray absorption near‐edge structure (HERFD‐XANES) and valence‐to‐core X‐ray emission (VtC‐XES) is demonstrated with measurement on Stryker's reagent (Cu6H6) and [Cu3(μ3‐H)(dpmppe)2](PF6)2 (Cu3H), alongside a non‐hydride copper compound (Cu‐I). The XANES analysis reveals that coordination geometries strongly influence the spectra, providing only indirect details about hydride coordination. The VtC‐XES analysis exhibits a distinct signal around 8975 eV, offering a diagnostic tool to identify hydride ligands. Theoretical calculations support and extend these findings by comparing hydride‐containing complexes with their hydride‐free counterparts.","lang":"eng"}],"title":"Detection and Characterization of Hydride Ligands in Copper Complexes by Hard X‐ray Spectroscopy","year":"2024","author":[{"first_name":"Lorena","id":"44418","last_name":"Fritsch","full_name":"Fritsch, Lorena"},{"first_name":"Pia","id":"46959","last_name":"Rehsies","full_name":"Rehsies, Pia"},{"full_name":"Barakat, Wael","last_name":"Barakat","first_name":"Wael"},{"first_name":"Deven P.","last_name":"Estes","full_name":"Estes, Deven P."},{"orcid":"0000-0002-9294-6076","full_name":"Bauer, Matthias","last_name":"Bauer","id":"47241","first_name":"Matthias"}],"publication_identifier":{"issn":["0947-6539","1521-3765"]},"user_id":"48467","doi":"10.1002/chem.202400357","date_created":"2024-05-07T08:41:11Z","publication_status":"published","article_type":"original","_id":"54024","status":"public","department":[{"_id":"306"}],"publisher":"Wiley","type":"journal_article","citation":{"chicago":"Fritsch, Lorena, Pia Rehsies, Wael Barakat, Deven P. Estes, and Matthias Bauer. “Detection and Characterization of Hydride Ligands in Copper Complexes by Hard X‐ray Spectroscopy.” <i>Chemistry – A European Journal</i>, 2024. <a href=\"https://doi.org/10.1002/chem.202400357\">https://doi.org/10.1002/chem.202400357</a>.","mla":"Fritsch, Lorena, et al. “Detection and Characterization of Hydride Ligands in Copper Complexes by Hard X‐ray Spectroscopy.” <i>Chemistry – A European Journal</i>, Wiley, 2024, doi:<a href=\"https://doi.org/10.1002/chem.202400357\">10.1002/chem.202400357</a>.","apa":"Fritsch, L., Rehsies, P., Barakat, W., Estes, D. P., &#38; Bauer, M. (2024). Detection and Characterization of Hydride Ligands in Copper Complexes by Hard X‐ray Spectroscopy. <i>Chemistry – A European Journal</i>. <a href=\"https://doi.org/10.1002/chem.202400357\">https://doi.org/10.1002/chem.202400357</a>","short":"L. Fritsch, P. Rehsies, W. Barakat, D.P. Estes, M. Bauer, Chemistry – A European Journal (2024).","ieee":"L. Fritsch, P. Rehsies, W. Barakat, D. P. Estes, and M. Bauer, “Detection and Characterization of Hydride Ligands in Copper Complexes by Hard X‐ray Spectroscopy,” <i>Chemistry – A European Journal</i>, 2024, doi: <a href=\"https://doi.org/10.1002/chem.202400357\">10.1002/chem.202400357</a>.","bibtex":"@article{Fritsch_Rehsies_Barakat_Estes_Bauer_2024, title={Detection and Characterization of Hydride Ligands in Copper Complexes by Hard X‐ray Spectroscopy}, DOI={<a href=\"https://doi.org/10.1002/chem.202400357\">10.1002/chem.202400357</a>}, journal={Chemistry – A European Journal}, publisher={Wiley}, author={Fritsch, Lorena and Rehsies, Pia and Barakat, Wael and Estes, Deven P. and Bauer, Matthias}, year={2024} }","ama":"Fritsch L, Rehsies P, Barakat W, Estes DP, Bauer M. Detection and Characterization of Hydride Ligands in Copper Complexes by Hard X‐ray Spectroscopy. <i>Chemistry – A European Journal</i>. Published online 2024. doi:<a href=\"https://doi.org/10.1002/chem.202400357\">10.1002/chem.202400357</a>"}}