Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds Hoppe, Axel Stepen, Arne J. Köring, Laura Paradies, Jan <jats:title>Abstract</jats:title><jats:p>The activation of C(<jats:italic>sp</jats:italic><jats:sup>3</jats:sup>)−F bonds by the commercially available catalyst B(C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub>)<jats:sub>3</jats:sub> is reported and applied in reactions with arenes, allylic, vinylic and acetylenic silanes, and olefins to achieve a variety of C−C bond formations (45 examples).</jats:p> Wiley 2024 info:eu-repo/semantics/article doc-type:article text http://purl.org/coar/resource_type/c_6501 https://ris.uni-paderborn.de/record/55371 Hoppe A, Stepen AJ, Köring L, Paradies J. Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds. <i>Advanced Synthesis &#38;amp; Catalysis</i>. 2024;366(13):2933-2938. doi:<a href="https://doi.org/10.1002/adsc.202400511">10.1002/adsc.202400511</a> eng info:eu-repo/semantics/altIdentifier/doi/10.1002/adsc.202400511 info:eu-repo/semantics/altIdentifier/issn/1615-4150 info:eu-repo/semantics/altIdentifier/issn/1615-4169 info:eu-repo/semantics/closedAccess