---
res:
  bibo_abstract:
  - <jats:title>Abstract</jats:title><jats:p>Understanding how water interacts with
    nanopores of carbonaceous electrodes is crucial for energy storage and conversion
    applications. A high surface area of carbonaceous materials does not necessarily
    need to translate to a high electrolyte‐solid interface area. Herein, we study
    the interaction of water with nanoporous C<jats:sub>1</jats:sub>N<jats:sub>1</jats:sub>
    materials to explain their very low specific capacitance in aqueous electrolytes
    despite their high surface area. Water was used to probe chemical environments,
    provided by pores of different sizes, in <jats:sup>1</jats:sup>H MAS NMR experiments.
    We observe that regardless of their high hydrophilicity, only a negligible portion
    of water can enter the nanopores of C<jats:sub>1</jats:sub>N<jats:sub>1</jats:sub>,
    in contrast to a reference pure carbon material with a similar pore structure.
    The common paradigm that water easily enters hydrophilic pores does not apply
    to C<jats:sub>1</jats:sub>N<jats:sub>1</jats:sub> nanopores below a few nanometers.
    Calorimetric and sorption experiments demonstrated strong water adsorption on
    the C<jats:sub>1</jats:sub>N<jats:sub>1</jats:sub> surface, which restricts water
    mobility across the interface and impedes its penetration into the nanopores.</jats:p>@eng
  bibo_authorlist:
  - foaf_Person:
      foaf_givenName: Irene
      foaf_name: Lamata‐Bermejo, Irene
      foaf_surname: Lamata‐Bermejo
  - foaf_Person:
      foaf_givenName: Waldemar
      foaf_name: Keil, Waldemar
      foaf_surname: Keil
  - foaf_Person:
      foaf_givenName: Karlo
      foaf_name: Nolkemper, Karlo
      foaf_surname: Nolkemper
  - foaf_Person:
      foaf_givenName: Julian
      foaf_name: Heske, Julian
      foaf_surname: Heske
  - foaf_Person:
      foaf_givenName: Janina
      foaf_name: Kossmann, Janina
      foaf_surname: Kossmann
  - foaf_Person:
      foaf_givenName: Hossam
      foaf_name: Elgabarty, Hossam
      foaf_surname: Elgabarty
  - foaf_Person:
      foaf_givenName: Martin
      foaf_name: Wortmann, Martin
      foaf_surname: Wortmann
  - foaf_Person:
      foaf_givenName: Mirosław
      foaf_name: Chorążewski, Mirosław
      foaf_surname: Chorążewski
  - foaf_Person:
      foaf_givenName: Claudia
      foaf_name: Schmidt, Claudia
      foaf_surname: Schmidt
      foaf_workInfoHomepage: http://www.librecat.org/personId=466
    orcid: 0000-0003-3179-9997
  - foaf_Person:
      foaf_givenName: Thomas D.
      foaf_name: Kühne, Thomas D.
      foaf_surname: Kühne
  - foaf_Person:
      foaf_givenName: Nieves
      foaf_name: López‐Salas, Nieves
      foaf_surname: López‐Salas
  - foaf_Person:
      foaf_givenName: Mateusz
      foaf_name: Odziomek, Mateusz
      foaf_surname: Odziomek
  bibo_doi: 10.1002/anie.202411493
  bibo_issue: '50'
  bibo_volume: 63
  dct_date: 2024^xs_gYear
  dct_isPartOf:
  - http://id.crossref.org/issn/1433-7851
  - http://id.crossref.org/issn/1521-3773
  dct_language: eng
  dct_publisher: Wiley@
  dct_title: 'Understanding the Wettability of C<sub>1</sub>N<sub>1</sub> (Sub)Nanopores:
    Implications for Porous Carbonaceous Electrodes@'
...