---
_id: '61848'
abstract:
- lang: eng
  text: <jats:title>Abstract</jats:title><jats:p>Understanding how water interacts
    with nanopores of carbonaceous electrodes is crucial for energy storage and conversion
    applications. A high surface area of carbonaceous materials does not necessarily
    need to translate to a high electrolyte‐solid interface area. Herein, we study
    the interaction of water with nanoporous C<jats:sub>1</jats:sub>N<jats:sub>1</jats:sub>
    materials to explain their very low specific capacitance in aqueous electrolytes
    despite their high surface area. Water was used to probe chemical environments,
    provided by pores of different sizes, in <jats:sup>1</jats:sup>H MAS NMR experiments.
    We observe that regardless of their high hydrophilicity, only a negligible portion
    of water can enter the nanopores of C<jats:sub>1</jats:sub>N<jats:sub>1</jats:sub>,
    in contrast to a reference pure carbon material with a similar pore structure.
    The common paradigm that water easily enters hydrophilic pores does not apply
    to C<jats:sub>1</jats:sub>N<jats:sub>1</jats:sub> nanopores below a few nanometers.
    Calorimetric and sorption experiments demonstrated strong water adsorption on
    the C<jats:sub>1</jats:sub>N<jats:sub>1</jats:sub> surface, which restricts water
    mobility across the interface and impedes its penetration into the nanopores.</jats:p>
article_number: e202411493
author:
- first_name: Irene
  full_name: Lamata‐Bermejo, Irene
  last_name: Lamata‐Bermejo
- first_name: Waldemar
  full_name: Keil, Waldemar
  last_name: Keil
- first_name: Karlo
  full_name: Nolkemper, Karlo
  last_name: Nolkemper
- first_name: Julian
  full_name: Heske, Julian
  last_name: Heske
- first_name: Janina
  full_name: Kossmann, Janina
  last_name: Kossmann
- first_name: Hossam
  full_name: Elgabarty, Hossam
  last_name: Elgabarty
- first_name: Martin
  full_name: Wortmann, Martin
  last_name: Wortmann
- first_name: Mirosław
  full_name: Chorążewski, Mirosław
  last_name: Chorążewski
- first_name: Claudia
  full_name: Schmidt, Claudia
  id: '466'
  last_name: Schmidt
  orcid: 0000-0003-3179-9997
- first_name: Thomas D.
  full_name: Kühne, Thomas D.
  last_name: Kühne
- first_name: Nieves
  full_name: López‐Salas, Nieves
  last_name: López‐Salas
- first_name: Mateusz
  full_name: Odziomek, Mateusz
  last_name: Odziomek
citation:
  ama: 'Lamata‐Bermejo I, Keil W, Nolkemper K, et al. Understanding the Wettability
    of C<sub>1</sub>N<sub>1</sub> (Sub)Nanopores: Implications for Porous Carbonaceous
    Electrodes. <i>Angewandte Chemie International Edition</i>. 2024;63(50). doi:<a
    href="https://doi.org/10.1002/anie.202411493">10.1002/anie.202411493</a>'
  apa: 'Lamata‐Bermejo, I., Keil, W., Nolkemper, K., Heske, J., Kossmann, J., Elgabarty,
    H., Wortmann, M., Chorążewski, M., Schmidt, C., Kühne, T. D., López‐Salas, N.,
    &#38; Odziomek, M. (2024). Understanding the Wettability of C<sub>1</sub>N<sub>1</sub>
    (Sub)Nanopores: Implications for Porous Carbonaceous Electrodes. <i>Angewandte
    Chemie International Edition</i>, <i>63</i>(50), Article e202411493. <a href="https://doi.org/10.1002/anie.202411493">https://doi.org/10.1002/anie.202411493</a>'
  bibtex: '@article{Lamata‐Bermejo_Keil_Nolkemper_Heske_Kossmann_Elgabarty_Wortmann_Chorążewski_Schmidt_Kühne_et
    al._2024, title={Understanding the Wettability of C<sub>1</sub>N<sub>1</sub> (Sub)Nanopores:
    Implications for Porous Carbonaceous Electrodes}, volume={63}, DOI={<a href="https://doi.org/10.1002/anie.202411493">10.1002/anie.202411493</a>},
    number={50e202411493}, journal={Angewandte Chemie International Edition}, publisher={Wiley},
    author={Lamata‐Bermejo, Irene and Keil, Waldemar and Nolkemper, Karlo and Heske,
    Julian and Kossmann, Janina and Elgabarty, Hossam and Wortmann, Martin and Chorążewski,
    Mirosław and Schmidt, Claudia and Kühne, Thomas D. and et al.}, year={2024} }'
  chicago: 'Lamata‐Bermejo, Irene, Waldemar Keil, Karlo Nolkemper, Julian Heske, Janina
    Kossmann, Hossam Elgabarty, Martin Wortmann, et al. “Understanding the Wettability
    of C<sub>1</sub>N<sub>1</sub> (Sub)Nanopores: Implications for Porous Carbonaceous
    Electrodes.” <i>Angewandte Chemie International Edition</i> 63, no. 50 (2024).
    <a href="https://doi.org/10.1002/anie.202411493">https://doi.org/10.1002/anie.202411493</a>.'
  ieee: 'I. Lamata‐Bermejo <i>et al.</i>, “Understanding the Wettability of C<sub>1</sub>N<sub>1</sub>
    (Sub)Nanopores: Implications for Porous Carbonaceous Electrodes,” <i>Angewandte
    Chemie International Edition</i>, vol. 63, no. 50, Art. no. e202411493, 2024,
    doi: <a href="https://doi.org/10.1002/anie.202411493">10.1002/anie.202411493</a>.'
  mla: 'Lamata‐Bermejo, Irene, et al. “Understanding the Wettability of C<sub>1</sub>N<sub>1</sub>
    (Sub)Nanopores: Implications for Porous Carbonaceous Electrodes.” <i>Angewandte
    Chemie International Edition</i>, vol. 63, no. 50, e202411493, Wiley, 2024, doi:<a
    href="https://doi.org/10.1002/anie.202411493">10.1002/anie.202411493</a>.'
  short: I. Lamata‐Bermejo, W. Keil, K. Nolkemper, J. Heske, J. Kossmann, H. Elgabarty,
    M. Wortmann, M. Chorążewski, C. Schmidt, T.D. Kühne, N. López‐Salas, M. Odziomek,
    Angewandte Chemie International Edition 63 (2024).
date_created: 2025-10-15T12:31:22Z
date_updated: 2025-10-15T13:23:57Z
department:
- _id: '2'
- _id: '315'
doi: 10.1002/anie.202411493
intvolume: '        63'
issue: '50'
language:
- iso: eng
publication: Angewandte Chemie International Edition
publication_identifier:
  issn:
  - 1433-7851
  - 1521-3773
publication_status: published
publisher: Wiley
status: public
title: 'Understanding the Wettability of C<sub>1</sub>N<sub>1</sub> (Sub)Nanopores:
  Implications for Porous Carbonaceous Electrodes'
type: journal_article
user_id: '466'
volume: 63
year: '2024'
...