{"citation":{"mla":"Longwitz, Lars, and Thomas Werner. “Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis.” <i>Angewandte Chemie International Edition</i>, vol. 59, no. 7, Wiley, 2020, pp. 2760–63, doi:<a href=\"https://doi.org/10.1002/anie.201912991\">10.1002/anie.201912991</a>.","ieee":"L. Longwitz and T. Werner, “Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis,” <i>Angewandte Chemie International Edition</i>, vol. 59, no. 7, pp. 2760–2763, 2020, doi: <a href=\"https://doi.org/10.1002/anie.201912991\">10.1002/anie.201912991</a>.","ama":"Longwitz L, Werner T. Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis. <i>Angewandte Chemie International Edition</i>. 2020;59(7):2760-2763. doi:<a href=\"https://doi.org/10.1002/anie.201912991\">10.1002/anie.201912991</a>","bibtex":"@article{Longwitz_Werner_2020, title={Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis}, volume={59}, DOI={<a href=\"https://doi.org/10.1002/anie.201912991\">10.1002/anie.201912991</a>}, number={7}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Longwitz, Lars and Werner, Thomas}, year={2020}, pages={2760–2763} }","short":"L. Longwitz, T. Werner, Angewandte Chemie International Edition 59 (2020) 2760–2763.","apa":"Longwitz, L., &#38; Werner, T. (2020). Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis. <i>Angewandte Chemie International Edition</i>, <i>59</i>(7), 2760–2763. <a href=\"https://doi.org/10.1002/anie.201912991\">https://doi.org/10.1002/anie.201912991</a>","chicago":"Longwitz, Lars, and Thomas Werner. “Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis.” <i>Angewandte Chemie International Edition</i> 59, no. 7 (2020): 2760–63. <a href=\"https://doi.org/10.1002/anie.201912991\">https://doi.org/10.1002/anie.201912991</a>."},"_id":"62102","year":"2020","issue":"7","publication":"Angewandte Chemie International Edition","author":[{"first_name":"Lars","full_name":"Longwitz, Lars","last_name":"Longwitz"},{"last_name":"Werner","orcid":"0000-0001-9025-3244","full_name":"Werner, Thomas","id":"89271","first_name":"Thomas"}],"status":"public","department":[{"_id":"35"},{"_id":"2"}],"doi":"10.1002/anie.201912991","language":[{"iso":"eng"}],"date_created":"2025-11-05T15:39:56Z","volume":59,"type":"journal_article","title":"Reduction of Activated Alkenes by P<sup>III</sup>/P<sup>V</sup> Redox Cycling Catalysis","keyword":["T2","T4","CSSD"],"page":"2760-2763","user_id":"89271","publisher":"Wiley","publication_status":"published","abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title><jats:p>The carbon–carbon double bond of unsaturated carbonyl compounds was readily reduced by using a phosphetane oxide catalyst in the presence of a simple organosilane as the terminal reductant and water as the hydrogen source. Quantitative hydrogenation was observed when 1.0 mol % of a methyl‐substituted phosphetane oxide was employed as the catalyst. The procedure is highly selective towards activated double bonds, tolerating a variety of functional groups that are usually prone to reduction. In total, 25 alkenes and two alkynes were hydrogenated to the corresponding alkanes in excellent yields of up to 99 %. Notably, less active poly(methylhydrosiloxane) could also be utilized as the terminal reductant. Mechanistic investigations revealed the phosphane as the catalyst resting state and a protonation/deprotonation sequence as the crucial step in the catalytic cycle.</jats:p>"}],"intvolume":"        59","date_updated":"2025-11-10T08:49:52Z","publication_identifier":{"issn":["1433-7851","1521-3773"]}}