---
res:
  bibo_abstract:
  - "<jats:title>Abstract</jats:title>\r\n                  <jats:p>\r\n                    Cationic
    gold catalyzed acetylene hydrochlorination represents a classical landmark in
    eliminating global mercury pollution, but their sustainable implementation is
    hindered by acetylene‐dependence design criteria and high operating temperatures.
    Herein, a platform of carbon‐supported single‐atoms Au catalysts (Au/BC and Au/NC)
    with polarized charge characteristics are developed via engineering Au sites with
    hosted B, N configurations. The negatively charged Au/BC catalyst unlocks the
    low‐temperature inactivity (413–423K) of the Au/NC catalyst while exhibiting superior
    catalytic performance in the 433–473K operating temperature range. We confirm
    that the classical scaling relationships on acetylene can be broken by narrowing
    the adsorption capacity between acetylene and HCl on Au\r\n                    <jats:sup>δ⁻</jats:sup>\r\n
    \                   sites via facilitating the back‐donation of\r\n                    <jats:italic>d</jats:italic>\r\n
    \                   electrons into the antibonding orbitals of acetylene. Prolonging
    the durability of Au catalysts is achieved through preceding an additional robust
    Au\r\n                    <jats:sup>δ⁻</jats:sup>\r\n                    → Au\r\n
    \                   <jats:sup>δ⁺</jats:sup>\r\n                    cycle prior
    to the classic Au\r\n                    <jats:sup>δ⁺</jats:sup>\r\n                    →
    Au\r\n                    <jats:sup>0</jats:sup>\r\n                    route.
    This work opens a promising avenue for low temperature vinyl chloride production.\r\n
    \                 </jats:p>@eng"
  bibo_authorlist:
  - foaf_Person:
      foaf_givenName: Chun
      foaf_name: Li, Chun
      foaf_surname: Li
  - foaf_Person:
      foaf_givenName: Ruoting
      foaf_name: Liu, Ruoting
      foaf_surname: Liu
  - foaf_Person:
      foaf_givenName: Zilong
      foaf_name: Zhang, Zilong
      foaf_surname: Zhang
  - foaf_Person:
      foaf_givenName: Fangmin
      foaf_name: Zuo, Fangmin
      foaf_surname: Zuo
  - foaf_Person:
      foaf_givenName: Tingting
      foaf_name: Jiang, Tingting
      foaf_surname: Jiang
  - foaf_Person:
      foaf_givenName: Haifeng
      foaf_name: Zhang, Haifeng
      foaf_surname: Zhang
  - foaf_Person:
      foaf_givenName: Bolin
      foaf_name: Wang, Bolin
      foaf_surname: Wang
  - foaf_Person:
      foaf_givenName: Nieves
      foaf_name: Lopez Salas, Nieves
      foaf_surname: Lopez Salas
      foaf_workInfoHomepage: http://www.librecat.org/personId=98120
    orcid: https://orcid.org/0000-0002-8438-9548
  bibo_doi: 10.1002/anie.202501370
  bibo_issue: '29'
  bibo_volume: 64
  dct_date: 2025^xs_gYear
  dct_isPartOf:
  - http://id.crossref.org/issn/1433-7851
  - http://id.crossref.org/issn/1521-3773
  dct_language: eng
  dct_publisher: Wiley@
  dct_title: Engineering Charge Polarized Au Sites for Low‐Temperature Acetylene Hydrochlorination@
...