{"publisher":"Wiley","publication":"Angewandte Chemie International Edition","user_id":"98120","article_number":"e202411493","issue":"50","year":"2024","_id":"62660","title":"Understanding the Wettability of C<sub>1</sub>N<sub>1</sub> (Sub)Nanopores: Implications for Porous Carbonaceous Electrodes","citation":{"chicago":"Lamata‐Bermejo, Irene, Waldemar Keil, Karlo Nolkemper, Julian Heske, Janina Kossmann, Hossam Elgabarty, Martin Wortmann, et al. “Understanding the Wettability of C<sub>1</sub>N<sub>1</sub> (Sub)Nanopores: Implications for Porous Carbonaceous Electrodes.” <i>Angewandte Chemie International Edition</i> 63, no. 50 (2024). <a href=\"https://doi.org/10.1002/anie.202411493\">https://doi.org/10.1002/anie.202411493</a>.","apa":"Lamata‐Bermejo, I., Keil, W., Nolkemper, K., Heske, J., Kossmann, J., Elgabarty, H., Wortmann, M., Chorążewski, M., Schmidt, C., Kühne, T. D., López‐Salas, N., &#38; Odziomek, M. (2024). Understanding the Wettability of C<sub>1</sub>N<sub>1</sub> (Sub)Nanopores: Implications for Porous Carbonaceous Electrodes. <i>Angewandte Chemie International Edition</i>, <i>63</i>(50), Article e202411493. <a href=\"https://doi.org/10.1002/anie.202411493\">https://doi.org/10.1002/anie.202411493</a>","short":"I. Lamata‐Bermejo, W. Keil, K. Nolkemper, J. Heske, J. Kossmann, H. Elgabarty, M. Wortmann, M. Chorążewski, C. Schmidt, T.D. Kühne, N. López‐Salas, M. Odziomek, Angewandte Chemie International Edition 63 (2024).","ama":"Lamata‐Bermejo I, Keil W, Nolkemper K, et al. Understanding the Wettability of C<sub>1</sub>N<sub>1</sub> (Sub)Nanopores: Implications for Porous Carbonaceous Electrodes. <i>Angewandte Chemie International Edition</i>. 2024;63(50). doi:<a href=\"https://doi.org/10.1002/anie.202411493\">10.1002/anie.202411493</a>","bibtex":"@article{Lamata‐Bermejo_Keil_Nolkemper_Heske_Kossmann_Elgabarty_Wortmann_Chorążewski_Schmidt_Kühne_et al._2024, title={Understanding the Wettability of C<sub>1</sub>N<sub>1</sub> (Sub)Nanopores: Implications for Porous Carbonaceous Electrodes}, volume={63}, DOI={<a href=\"https://doi.org/10.1002/anie.202411493\">10.1002/anie.202411493</a>}, number={50e202411493}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Lamata‐Bermejo, Irene and Keil, Waldemar and Nolkemper, Karlo and Heske, Julian and Kossmann, Janina and Elgabarty, Hossam and Wortmann, Martin and Chorążewski, Mirosław and Schmidt, Claudia and Kühne, Thomas D. and et al.}, year={2024} }","ieee":"I. Lamata‐Bermejo <i>et al.</i>, “Understanding the Wettability of C<sub>1</sub>N<sub>1</sub> (Sub)Nanopores: Implications for Porous Carbonaceous Electrodes,” <i>Angewandte Chemie International Edition</i>, vol. 63, no. 50, Art. no. e202411493, 2024, doi: <a href=\"https://doi.org/10.1002/anie.202411493\">10.1002/anie.202411493</a>.","mla":"Lamata‐Bermejo, Irene, et al. “Understanding the Wettability of C<sub>1</sub>N<sub>1</sub> (Sub)Nanopores: Implications for Porous Carbonaceous Electrodes.” <i>Angewandte Chemie International Edition</i>, vol. 63, no. 50, e202411493, Wiley, 2024, doi:<a href=\"https://doi.org/10.1002/anie.202411493\">10.1002/anie.202411493</a>."},"volume":63,"publication_identifier":{"issn":["1433-7851","1521-3773"]},"type":"journal_article","date_created":"2025-11-27T13:14:44Z","date_updated":"2025-12-03T14:59:06Z","intvolume":"        63","language":[{"iso":"eng"}],"abstract":[{"text":"<jats:title>Abstract</jats:title><jats:p>Understanding how water interacts with nanopores of carbonaceous electrodes is crucial for energy storage and conversion applications. A high surface area of carbonaceous materials does not necessarily need to translate to a high electrolyte‐solid interface area. Herein, we study the interaction of water with nanoporous C<jats:sub>1</jats:sub>N<jats:sub>1</jats:sub> materials to explain their very low specific capacitance in aqueous electrolytes despite their high surface area. Water was used to probe chemical environments, provided by pores of different sizes, in <jats:sup>1</jats:sup>H MAS NMR experiments. We observe that regardless of their high hydrophilicity, only a negligible portion of water can enter the nanopores of C<jats:sub>1</jats:sub>N<jats:sub>1</jats:sub>, in contrast to a reference pure carbon material with a similar pore structure. The common paradigm that water easily enters hydrophilic pores does not apply to C<jats:sub>1</jats:sub>N<jats:sub>1</jats:sub> nanopores below a few nanometers. Calorimetric and sorption experiments demonstrated strong water adsorption on the C<jats:sub>1</jats:sub>N<jats:sub>1</jats:sub> surface, which restricts water mobility across the interface and impedes its penetration into the nanopores.</jats:p>","lang":"eng"}],"doi":"10.1002/anie.202411493","publication_status":"published","author":[{"first_name":"Irene","last_name":"Lamata‐Bermejo","full_name":"Lamata‐Bermejo, Irene"},{"last_name":"Keil","full_name":"Keil, Waldemar","first_name":"Waldemar"},{"full_name":"Nolkemper, Karlo","last_name":"Nolkemper","first_name":"Karlo"},{"first_name":"Julian","last_name":"Heske","full_name":"Heske, Julian"},{"full_name":"Kossmann, Janina","last_name":"Kossmann","first_name":"Janina"},{"last_name":"Elgabarty","full_name":"Elgabarty, Hossam","first_name":"Hossam"},{"last_name":"Wortmann","full_name":"Wortmann, Martin","first_name":"Martin"},{"full_name":"Chorążewski, Mirosław","last_name":"Chorążewski","first_name":"Mirosław"},{"full_name":"Schmidt, Claudia","last_name":"Schmidt","first_name":"Claudia"},{"full_name":"Kühne, Thomas D.","last_name":"Kühne","first_name":"Thomas D."},{"first_name":"Nieves","last_name":"López‐Salas","full_name":"López‐Salas, Nieves"},{"full_name":"Odziomek, Mateusz","last_name":"Odziomek","first_name":"Mateusz"}],"status":"public"}