[{"date_created":"2025-11-27T13:16:31Z","publication":"Advanced Science","publisher":"Wiley","language":[{"iso":"eng"}],"publication_identifier":{"issn":["2198-3844","2198-3844"]},"year":"2023","type":"journal_article","status":"public","_id":"62675","volume":10,"article_number":"2300099","issue":"13","date_updated":"2026-01-08T13:11:24Z","title":"Green Light Photoelectrocatalysis with Sulfur‐Doped Carbon Nitride: Using Triazole‐Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions","author":[{"first_name":"Maria","full_name":"Jerigova, Maria","last_name":"Jerigova"},{"first_name":"Yevheniia","full_name":"Markushyna, Yevheniia","last_name":"Markushyna"},{"full_name":"Teixeira, Ivo F.","first_name":"Ivo F.","last_name":"Teixeira"},{"first_name":"Bolortuya","full_name":"Badamdorj, Bolortuya","last_name":"Badamdorj"},{"first_name":"Mark","full_name":"Isaacs, Mark","last_name":"Isaacs"},{"full_name":"Cruz, Daniel","first_name":"Daniel","last_name":"Cruz"},{"last_name":"Lauermann","full_name":"Lauermann, Iver","first_name":"Iver"},{"full_name":"Muñoz‐Márquez, Miguel Ángel","first_name":"Miguel Ángel","last_name":"Muñoz‐Márquez"},{"full_name":"Tarakina, Nadezda V.","first_name":"Nadezda V.","last_name":"Tarakina"},{"orcid":"https://orcid.org/0000-0002-8438-9548","first_name":"Nieves","full_name":"Lopez Salas, Nieves","last_name":"Lopez Salas","id":"98120"},{"last_name":"Savateev","full_name":"Savateev, Oleksandr","first_name":"Oleksandr"},{"first_name":"Pablo","full_name":"Jimenéz‐Calvo, Pablo","last_name":"Jimenéz‐Calvo"}],"abstract":[{"lang":"eng","text":"<jats:title>Abstract</jats:title>\r\n                  <jats:p>\r\n                    Materials dictate carbon neutral industrial chemical processes. Visible‐light photoelectrocatalysts from abundant resources will play a key role in exploiting solar irradiation. Anionic doping via pre‐organization of precursors and further co‐polymerization creates tuneable semiconductors. Triazole derivative‐purpald, an unexplored precursor with sulfur (S) container, combined in different initial ratios with melamine during one solid‐state polycondensation with two thermal steps yields hybrid S‐doped carbon nitrides (C\r\n                    <jats:sub>3</jats:sub>\r\n                    N\r\n                    <jats:sub>4</jats:sub>\r\n                    ). The series of S‐doped/C\r\n                    <jats:sub>3</jats:sub>\r\n                    N\r\n                    <jats:sub>4</jats:sub>\r\n                    ‐based materials show enhanced optical, electronic, structural, textural, and morphological properties and exhibit higher performance in organic benzylamine photooxidation, oxygen evolution, and similar energy storage (capacitor brief investigation). 50M‐50P exhibits the highest photooxidation conversion (84 ± 3%) of benzylamine to imine at 535 nm – green light for 48 h, due to a discrete shoulder (≈700) nm, high sulfur content, preservation of crystal size, new intraband energy states, structural defects by layer distortion, and 10–16 nm pores with arbitrary depth. This work innovates by studying the concomitant relationships between: 1) the precursor decomposition while C\r\n                    <jats:sub>3</jats:sub>\r\n                    N\r\n                    <jats:sub>4</jats:sub>\r\n                    is formed, 2) the insertion of S impurities, 3) the S‐doped C\r\n                    <jats:sub>3</jats:sub>\r\n                    N\r\n                    <jats:sub>4</jats:sub>\r\n                    property‐activity relationships, and 4) combinatorial surface, bulk, structural, optical, and electronic characterization analysis. This work contributes to the development of disordered long‐visible‐light photocatalysts for solar energy conversion and storage.\r\n                  </jats:p>"}],"intvolume":"        10","doi":"10.1002/advs.202300099","citation":{"ieee":"M. Jerigova <i>et al.</i>, “Green Light Photoelectrocatalysis with Sulfur‐Doped Carbon Nitride: Using Triazole‐Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions,” <i>Advanced Science</i>, vol. 10, no. 13, Art. no. 2300099, 2023, doi: <a href=\"https://doi.org/10.1002/advs.202300099\">10.1002/advs.202300099</a>.","chicago":"Jerigova, Maria, Yevheniia Markushyna, Ivo F. Teixeira, Bolortuya Badamdorj, Mark Isaacs, Daniel Cruz, Iver Lauermann, et al. “Green Light Photoelectrocatalysis with Sulfur‐Doped Carbon Nitride: Using Triazole‐Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions.” <i>Advanced Science</i> 10, no. 13 (2023). <a href=\"https://doi.org/10.1002/advs.202300099\">https://doi.org/10.1002/advs.202300099</a>.","apa":"Jerigova, M., Markushyna, Y., Teixeira, I. F., Badamdorj, B., Isaacs, M., Cruz, D., Lauermann, I., Muñoz‐Márquez, M. Á., Tarakina, N. V., Lopez Salas, N., Savateev, O., &#38; Jimenéz‐Calvo, P. (2023). Green Light Photoelectrocatalysis with Sulfur‐Doped Carbon Nitride: Using Triazole‐Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions. <i>Advanced Science</i>, <i>10</i>(13), Article 2300099. <a href=\"https://doi.org/10.1002/advs.202300099\">https://doi.org/10.1002/advs.202300099</a>","ama":"Jerigova M, Markushyna Y, Teixeira IF, et al. Green Light Photoelectrocatalysis with Sulfur‐Doped Carbon Nitride: Using Triazole‐Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions. <i>Advanced Science</i>. 2023;10(13). doi:<a href=\"https://doi.org/10.1002/advs.202300099\">10.1002/advs.202300099</a>","short":"M. Jerigova, Y. Markushyna, I.F. Teixeira, B. Badamdorj, M. Isaacs, D. Cruz, I. Lauermann, M.Á. Muñoz‐Márquez, N.V. Tarakina, N. Lopez Salas, O. Savateev, P. Jimenéz‐Calvo, Advanced Science 10 (2023).","bibtex":"@article{Jerigova_Markushyna_Teixeira_Badamdorj_Isaacs_Cruz_Lauermann_Muñoz‐Márquez_Tarakina_Lopez Salas_et al._2023, title={Green Light Photoelectrocatalysis with Sulfur‐Doped Carbon Nitride: Using Triazole‐Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions}, volume={10}, DOI={<a href=\"https://doi.org/10.1002/advs.202300099\">10.1002/advs.202300099</a>}, number={132300099}, journal={Advanced Science}, publisher={Wiley}, author={Jerigova, Maria and Markushyna, Yevheniia and Teixeira, Ivo F. and Badamdorj, Bolortuya and Isaacs, Mark and Cruz, Daniel and Lauermann, Iver and Muñoz‐Márquez, Miguel Ángel and Tarakina, Nadezda V. and Lopez Salas, Nieves and et al.}, year={2023} }","mla":"Jerigova, Maria, et al. “Green Light Photoelectrocatalysis with Sulfur‐Doped Carbon Nitride: Using Triazole‐Purpald for Enhanced Benzylamine Oxidation and Oxygen Evolution Reactions.” <i>Advanced Science</i>, vol. 10, no. 13, 2300099, Wiley, 2023, doi:<a href=\"https://doi.org/10.1002/advs.202300099\">10.1002/advs.202300099</a>."},"publication_status":"published","user_id":"98120"}]