{"year":"2021","citation":{"ama":"Azimzadeh Sani M, Pavlopoulos NG, Pezzotti S, et al. Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer. <i>Angewandte Chemie International Edition</i>. 2021;61(5). doi:<a href=\"https://doi.org/10.1002/anie.202112679\">10.1002/anie.202112679</a>","apa":"Azimzadeh Sani, M., Pavlopoulos, N. G., Pezzotti, S., Serva, A., Cignoni, P., Linnemann, J., Salanne, M., Gaigeot, M., &#38; Tschulik, K. (2021). Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer. <i>Angewandte Chemie International Edition</i>, <i>61</i>(5), Article e202112679. <a href=\"https://doi.org/10.1002/anie.202112679\">https://doi.org/10.1002/anie.202112679</a>","chicago":"Azimzadeh Sani, Mahnaz, Nicholas G. Pavlopoulos, Simone Pezzotti, Alessandra Serva, Paolo Cignoni, Julia Linnemann, Mathieu Salanne, Marie‐Pierre Gaigeot, and Kristina Tschulik. “Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer.” <i>Angewandte Chemie International Edition</i> 61, no. 5 (2021). <a href=\"https://doi.org/10.1002/anie.202112679\">https://doi.org/10.1002/anie.202112679</a>.","short":"M. Azimzadeh Sani, N.G. Pavlopoulos, S. Pezzotti, A. Serva, P. Cignoni, J. Linnemann, M. Salanne, M. Gaigeot, K. Tschulik, Angewandte Chemie International Edition 61 (2021).","bibtex":"@article{Azimzadeh Sani_Pavlopoulos_Pezzotti_Serva_Cignoni_Linnemann_Salanne_Gaigeot_Tschulik_2021, title={Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer}, volume={61}, DOI={<a href=\"https://doi.org/10.1002/anie.202112679\">10.1002/anie.202112679</a>}, number={5e202112679}, journal={Angewandte Chemie International Edition}, publisher={Wiley}, author={Azimzadeh Sani, Mahnaz and Pavlopoulos, Nicholas G. and Pezzotti, Simone and Serva, Alessandra and Cignoni, Paolo and Linnemann, Julia and Salanne, Mathieu and Gaigeot, Marie‐Pierre and Tschulik, Kristina}, year={2021} }","ieee":"M. Azimzadeh Sani <i>et al.</i>, “Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer,” <i>Angewandte Chemie International Edition</i>, vol. 61, no. 5, Art. no. e202112679, 2021, doi: <a href=\"https://doi.org/10.1002/anie.202112679\">10.1002/anie.202112679</a>.","mla":"Azimzadeh Sani, Mahnaz, et al. “Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer.” <i>Angewandte Chemie International Edition</i>, vol. 61, no. 5, e202112679, Wiley, 2021, doi:<a href=\"https://doi.org/10.1002/anie.202112679\">10.1002/anie.202112679</a>."},"_id":"62806","publication":"Angewandte Chemie International Edition","issue":"5","main_file_link":[{"open_access":"1"}],"doi":"10.1002/anie.202112679","language":[{"iso":"eng"}],"oa":"1","status":"public","author":[{"last_name":"Azimzadeh Sani","full_name":"Azimzadeh Sani, Mahnaz","first_name":"Mahnaz"},{"first_name":"Nicholas G.","full_name":"Pavlopoulos, Nicholas G.","last_name":"Pavlopoulos"},{"first_name":"Simone","full_name":"Pezzotti, Simone","last_name":"Pezzotti"},{"full_name":"Serva, Alessandra","last_name":"Serva","first_name":"Alessandra"},{"full_name":"Cignoni, Paolo","last_name":"Cignoni","first_name":"Paolo"},{"full_name":"Linnemann, Julia","orcid":"0000-0001-6883-5424","last_name":"Linnemann","id":"116779","first_name":"Julia"},{"full_name":"Salanne, Mathieu","last_name":"Salanne","first_name":"Mathieu"},{"full_name":"Gaigeot, Marie‐Pierre","last_name":"Gaigeot","first_name":"Marie‐Pierre"},{"first_name":"Kristina","full_name":"Tschulik, Kristina","last_name":"Tschulik"}],"department":[{"_id":"985"}],"type":"journal_article","volume":61,"date_created":"2025-12-03T15:39:25Z","title":"Unexpectedly High Capacitance of the Metal Nanoparticle/Water Interface: Molecular‐Level Insights into the Electrical Double Layer","keyword":["single-entity electrochemistry","electrical double layer","supercapacitor","nanoparticles"],"user_id":"116779","publisher":"Wiley","article_number":"e202112679","publication_status":"published","quality_controlled":"1","abstract":[{"text":"The electrical double‐layer plays a key role in important interfacial electrochemical processes from catalysis to energy storage and corrosion. Therefore, understanding its structure is crucial for the progress of sustainable technologies. We extract new physico‐chemical information on the capacitance and structure of the electrical double‐layer of platinum and gold nanoparticles at the molecular level, employing single nanoparticle electrochemistry. The charge storage ability of the solid/liquid interface is larger by one order‐of‐magnitude than predicted by the traditional mean‐field models of the double‐layer such as the Gouy–Chapman–Stern model. Performing molecular dynamics simulations, we investigate the possible relationship between the measured high capacitance and adsorption strength of the water adlayer formed at the metal surface. These insights may launch the active tuning of solid–solvent and solvent–solvent interactions as an innovative design strategy to transform energy technologies towards superior performance and sustainability.","lang":"eng"}],"extern":"1","article_type":"original","publication_identifier":{"issn":["1433-7851","1521-3773"]},"date_updated":"2025-12-03T16:31:54Z","intvolume":"        61"}