{"issue":"1","publication_identifier":{"issn":["0021-9568"]},"intvolume":"        70","page":"600–606","citation":{"mla":"Hoffmann, Markus M., et al. “Thermal Behavior of N-Octanol and Related Ether Alcohols.” <i>Journal of Chemical &#38; Engineering Data</i>, vol. 70, no. 1, American Chemical Society, 2025, pp. 600–606, doi:<a href=\"https://doi.org/10.1021/acs.jced.4c00525\">10.1021/acs.jced.4c00525</a>.","short":"M.M. Hoffmann, T. Gutmann, G. Buntkowsky, Journal of Chemical &#38; Engineering Data 70 (2025) 600–606.","bibtex":"@article{Hoffmann_Gutmann_Buntkowsky_2025, title={Thermal Behavior of n-Octanol and Related Ether Alcohols}, volume={70}, DOI={<a href=\"https://doi.org/10.1021/acs.jced.4c00525\">10.1021/acs.jced.4c00525</a>}, number={1}, journal={Journal of Chemical &#38; Engineering Data}, publisher={American Chemical Society}, author={Hoffmann, Markus M. and Gutmann, Torsten and Buntkowsky, Gerd}, year={2025}, pages={600–606} }","apa":"Hoffmann, M. M., Gutmann, T., &#38; Buntkowsky, G. (2025). Thermal Behavior of n-Octanol and Related Ether Alcohols. <i>Journal of Chemical &#38; Engineering Data</i>, <i>70</i>(1), 600–606. <a href=\"https://doi.org/10.1021/acs.jced.4c00525\">https://doi.org/10.1021/acs.jced.4c00525</a>","chicago":"Hoffmann, Markus M., Torsten Gutmann, and Gerd Buntkowsky. “Thermal Behavior of N-Octanol and Related Ether Alcohols.” <i>Journal of Chemical &#38; Engineering Data</i> 70, no. 1 (2025): 600–606. <a href=\"https://doi.org/10.1021/acs.jced.4c00525\">https://doi.org/10.1021/acs.jced.4c00525</a>.","ieee":"M. M. Hoffmann, T. Gutmann, and G. Buntkowsky, “Thermal Behavior of n-Octanol and Related Ether Alcohols,” <i>Journal of Chemical &#38; Engineering Data</i>, vol. 70, no. 1, pp. 600–606, 2025, doi: <a href=\"https://doi.org/10.1021/acs.jced.4c00525\">10.1021/acs.jced.4c00525</a>.","ama":"Hoffmann MM, Gutmann T, Buntkowsky G. Thermal Behavior of n-Octanol and Related Ether Alcohols. <i>Journal of Chemical &#38; Engineering Data</i>. 2025;70(1):600–606. doi:<a href=\"https://doi.org/10.1021/acs.jced.4c00525\">10.1021/acs.jced.4c00525</a>"},"year":"2025","volume":70,"date_created":"2026-02-07T15:44:13Z","author":[{"first_name":"Markus M.","last_name":"Hoffmann","full_name":"Hoffmann, Markus M."},{"last_name":"Gutmann","id":"118165","full_name":"Gutmann, Torsten","first_name":"Torsten"},{"first_name":"Gerd","full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky"}],"publisher":"American Chemical Society","date_updated":"2026-02-17T16:16:57Z","doi":"10.1021/acs.jced.4c00525","title":"Thermal Behavior of n-Octanol and Related Ether Alcohols","publication":"Journal of Chemical & Engineering Data","type":"journal_article","status":"public","abstract":[{"text":"The thermal behavior of n-octanol and related ether alcohols has been studied by differential scanning calorimetry (DSC). The melting point, heat of fusion, and isobaric heat capacities of n-octanol obtained from the DSC measurements are in good agreement with literature values. The ether alcohols display kinetic barriers for forming a solid phase during cooldown. These barriers are least for 6-methoxyhexanol that forms a solid upon cooling except for the highest measured temperature change rate of 40 K·min–1, followed by 4-propoxybutanol that forms a solid during cooldown only at low cooling rates. 2-Pentoxyethanol and 5-ethoxypentanol form a solid during the heating cycle that then melts again upon further heating. 3-Butoxypropanol does not display any exo- and endothermic features for all measured temperature change rates. Consequently, new data on melting point and heats of fusion are reported for the ether alcohols except for 3-butoxypropanol. New isobaric heat capacities are presented as well for the liquid phase of these ether alcohols. The thermal behavior of n-octanol and related ether alcohols has been studied by differential scanning calorimetry (DSC). The melting point, heat of fusion, and isobaric heat capacities of n-octanol obtained from the DSC measurements are in good agreement with literature values. The ether alcohols display kinetic barriers for forming a solid phase during cooldown. These barriers are least for 6-methoxyhexanol that forms a solid upon cooling except for the highest measured temperature change rate of 40 K·min–1, followed by 4-propoxybutanol that forms a solid during cooldown only at low cooling rates. 2-Pentoxyethanol and 5-ethoxypentanol form a solid during the heating cycle that then melts again upon further heating. 3-Butoxypropanol does not display any exo- and endothermic features for all measured temperature change rates. Consequently, new data on melting point and heats of fusion are reported for the ether alcohols except for 3-butoxypropanol. New isobaric heat capacities are presented as well for the liquid phase of these ether alcohols.","lang":"eng"}],"user_id":"100715","_id":"63981","extern":"1","language":[{"iso":"eng"}]}