{"language":[{"iso":"eng"}],"extern":"1","user_id":"100715","_id":"63993","status":"public","abstract":[{"lang":"eng","text":"A synthetic strategy to β-silylphospholes with three methoxy, ethoxy, chloro, hydrido, or phenyl substituents at silicon has been developed, starting from trimethoxy, triethoxy, or triphenyl silyl substituted phenyl phosphanides and 1,4-diphenyl-1,3-butadiyne. These trifunctional silylphospholes were attached to the surface of uniform spheric silica particles (15 μm) and, for comparison, to a polyhedral silsesquioxane (POSS)–trisilanol as a molecular model to explore their luminescent properties in comparison with the free phospholes. Density functional theory calculations were performed to investigate any electronic perturbation of the phosphole system by the trifunctional silyl anchoring unit. For the immobilized phospholes, cross-polarization magic-angle-spinning NMR measurements (13C, 29Si, and 31P) were carried out to explore the bonding situation to the silica surface. Thermogravimetric analysis and X-ray photoelectron spectroscopy measurements were performed to approximate the amount of phospholes covering the silica surface. Identity and purity of all novel phospholes have been established with standard techniques (multinuclear NMR, mass spectrometry, and elemental analysis) and X-ray diffraction for the POSS derivative."}],"type":"journal_article","publication":"Inorganic Chemistry","doi":"10.1021/acs.inorgchem.1c01775","title":"Trifunctional Silyl Groups as Anchoring Units in the Preparation of Luminescent Phosphole–Silica Hybrids","date_created":"2026-02-07T15:47:54Z","author":[{"full_name":"Klintuch, Dieter","last_name":"Klintuch","first_name":"Dieter"},{"first_name":"Mark V.","full_name":"Höfler, Mark V.","last_name":"Höfler"},{"last_name":"Wissel","full_name":"Wissel, Till","first_name":"Till"},{"last_name":"Bruhn","full_name":"Bruhn, Clemens","first_name":"Clemens"},{"id":"118165","full_name":"Gutmann, Torsten","last_name":"Gutmann","first_name":"Torsten"},{"first_name":"Rudolf","last_name":"Pietschnig","full_name":"Pietschnig, Rudolf"}],"volume":60,"date_updated":"2026-02-17T16:16:17Z","publisher":"American Chemical Society","citation":{"ama":"Klintuch D, Höfler MV, Wissel T, Bruhn C, Gutmann T, Pietschnig R. Trifunctional Silyl Groups as Anchoring Units in the Preparation of Luminescent Phosphole–Silica Hybrids. <i>Inorganic Chemistry</i>. 2021;60(18):14263–14274. doi:<a href=\"https://doi.org/10.1021/acs.inorgchem.1c01775\">10.1021/acs.inorgchem.1c01775</a>","chicago":"Klintuch, Dieter, Mark V. Höfler, Till Wissel, Clemens Bruhn, Torsten Gutmann, and Rudolf Pietschnig. “Trifunctional Silyl Groups as Anchoring Units in the Preparation of Luminescent Phosphole–Silica Hybrids.” <i>Inorganic Chemistry</i> 60, no. 18 (2021): 14263–14274. <a href=\"https://doi.org/10.1021/acs.inorgchem.1c01775\">https://doi.org/10.1021/acs.inorgchem.1c01775</a>.","ieee":"D. Klintuch, M. V. Höfler, T. Wissel, C. Bruhn, T. Gutmann, and R. Pietschnig, “Trifunctional Silyl Groups as Anchoring Units in the Preparation of Luminescent Phosphole–Silica Hybrids,” <i>Inorganic Chemistry</i>, vol. 60, no. 18, pp. 14263–14274, 2021, doi: <a href=\"https://doi.org/10.1021/acs.inorgchem.1c01775\">10.1021/acs.inorgchem.1c01775</a>.","mla":"Klintuch, Dieter, et al. “Trifunctional Silyl Groups as Anchoring Units in the Preparation of Luminescent Phosphole–Silica Hybrids.” <i>Inorganic Chemistry</i>, vol. 60, no. 18, American Chemical Society, 2021, pp. 14263–14274, doi:<a href=\"https://doi.org/10.1021/acs.inorgchem.1c01775\">10.1021/acs.inorgchem.1c01775</a>.","bibtex":"@article{Klintuch_Höfler_Wissel_Bruhn_Gutmann_Pietschnig_2021, title={Trifunctional Silyl Groups as Anchoring Units in the Preparation of Luminescent Phosphole–Silica Hybrids}, volume={60}, DOI={<a href=\"https://doi.org/10.1021/acs.inorgchem.1c01775\">10.1021/acs.inorgchem.1c01775</a>}, number={18}, journal={Inorganic Chemistry}, publisher={American Chemical Society}, author={Klintuch, Dieter and Höfler, Mark V. and Wissel, Till and Bruhn, Clemens and Gutmann, Torsten and Pietschnig, Rudolf}, year={2021}, pages={14263–14274} }","short":"D. Klintuch, M.V. Höfler, T. Wissel, C. Bruhn, T. Gutmann, R. Pietschnig, Inorganic Chemistry 60 (2021) 14263–14274.","apa":"Klintuch, D., Höfler, M. V., Wissel, T., Bruhn, C., Gutmann, T., &#38; Pietschnig, R. (2021). Trifunctional Silyl Groups as Anchoring Units in the Preparation of Luminescent Phosphole–Silica Hybrids. <i>Inorganic Chemistry</i>, <i>60</i>(18), 14263–14274. <a href=\"https://doi.org/10.1021/acs.inorgchem.1c01775\">https://doi.org/10.1021/acs.inorgchem.1c01775</a>"},"intvolume":"        60","page":"14263–14274","year":"2021","issue":"18"}