{"type":"journal_article","publication":"Catalysis Science & Technology","abstract":[{"text":"Three chiral dirhodium coordination polymers Rh2–Ln (n = 1–3) have been synthesized via ligand exchange between dirhodium trifluoroacetate Rh2(TFA)4 and differently sized chiral dicarboxylic acids derived from l-tert-leucine. SEM images indicate that the Rh2–Ln (n = 1–3) polymers have a lamellar structure. XPS data demonstrate that the oxidation state of rhodium in the dirhodium nodes is maintained during the synthesis of the polymers. The coordination polymers have been further characterized by FTIR, 1H → 13C CP MAS NMR and 19F MAS NMR spectroscopy to prove the formation of polymers via ligand exchange. Although the quantitative 19F MAS NMR spectra reveal incomplete ligand substitution in the coordination polymers, these catalysts show excellent activity and selectivity in the asymmetric cyclopropanation reaction between styrene and diazooxindole. In particular, the enantioselectivity has been significantly improved compared with previously designed dirhodium coordination polymers, which were synthesized from aromatic dicarboxylic acids derived from l-phenylalanine. Meanwhile, the dirhodium polymers can be easily recycled five times without significant reduction in their catalytic efficiency.","lang":"eng"}],"status":"public","_id":"64006","user_id":"100715","extern":"1","language":[{"iso":"eng"}],"publication_identifier":{"issn":["2044-4753"]},"issue":"10","year":"2021","citation":{"chicago":"Li, Zhenzhong, Lorenz Rösler, Till Wissel, Hergen Breitzke, Kathrin Hofmann, Hans-Heinrich Limbach, Torsten Gutmann, and Gerd Buntkowsky. “Design and Characterization of Novel Dirhodium Coordination Polymers – the Impact of Ligand Size on Selectivity in Asymmetric Cyclopropanation.” <i>Catalysis Science &#38; Technology</i> 11, no. 10 (2021): 3481–3492. <a href=\"https://doi.org/10.1039/D1CY00109D\">https://doi.org/10.1039/D1CY00109D</a>.","ieee":"Z. Li <i>et al.</i>, “Design and characterization of novel dirhodium coordination polymers – the impact of ligand size on selectivity in asymmetric cyclopropanation,” <i>Catalysis Science &#38; Technology</i>, vol. 11, no. 10, pp. 3481–3492, 2021, doi: <a href=\"https://doi.org/10.1039/D1CY00109D\">10.1039/D1CY00109D</a>.","ama":"Li Z, Rösler L, Wissel T, et al. Design and characterization of novel dirhodium coordination polymers – the impact of ligand size on selectivity in asymmetric cyclopropanation. <i>Catalysis Science &#38; Technology</i>. 2021;11(10):3481–3492. doi:<a href=\"https://doi.org/10.1039/D1CY00109D\">10.1039/D1CY00109D</a>","mla":"Li, Zhenzhong, et al. “Design and Characterization of Novel Dirhodium Coordination Polymers – the Impact of Ligand Size on Selectivity in Asymmetric Cyclopropanation.” <i>Catalysis Science &#38; Technology</i>, vol. 11, no. 10, The Royal Society of Chemistry, 2021, pp. 3481–3492, doi:<a href=\"https://doi.org/10.1039/D1CY00109D\">10.1039/D1CY00109D</a>.","bibtex":"@article{Li_Rösler_Wissel_Breitzke_Hofmann_Limbach_Gutmann_Buntkowsky_2021, title={Design and characterization of novel dirhodium coordination polymers – the impact of ligand size on selectivity in asymmetric cyclopropanation}, volume={11}, DOI={<a href=\"https://doi.org/10.1039/D1CY00109D\">10.1039/D1CY00109D</a>}, number={10}, journal={Catalysis Science &#38; Technology}, publisher={The Royal Society of Chemistry}, author={Li, Zhenzhong and Rösler, Lorenz and Wissel, Till and Breitzke, Hergen and Hofmann, Kathrin and Limbach, Hans-Heinrich and Gutmann, Torsten and Buntkowsky, Gerd}, year={2021}, pages={3481–3492} }","short":"Z. Li, L. Rösler, T. Wissel, H. Breitzke, K. Hofmann, H.-H. Limbach, T. Gutmann, G. Buntkowsky, Catalysis Science &#38; Technology 11 (2021) 3481–3492.","apa":"Li, Z., Rösler, L., Wissel, T., Breitzke, H., Hofmann, K., Limbach, H.-H., Gutmann, T., &#38; Buntkowsky, G. (2021). Design and characterization of novel dirhodium coordination polymers – the impact of ligand size on selectivity in asymmetric cyclopropanation. <i>Catalysis Science &#38; Technology</i>, <i>11</i>(10), 3481–3492. <a href=\"https://doi.org/10.1039/D1CY00109D\">https://doi.org/10.1039/D1CY00109D</a>"},"page":"3481–3492","intvolume":"        11","date_updated":"2026-02-17T16:15:33Z","publisher":"The Royal Society of Chemistry","date_created":"2026-02-07T15:55:39Z","author":[{"first_name":"Zhenzhong","last_name":"Li","full_name":"Li, Zhenzhong"},{"last_name":"Rösler","full_name":"Rösler, Lorenz","first_name":"Lorenz"},{"first_name":"Till","last_name":"Wissel","full_name":"Wissel, Till"},{"last_name":"Breitzke","full_name":"Breitzke, Hergen","first_name":"Hergen"},{"first_name":"Kathrin","full_name":"Hofmann, Kathrin","last_name":"Hofmann"},{"first_name":"Hans-Heinrich","last_name":"Limbach","full_name":"Limbach, Hans-Heinrich"},{"first_name":"Torsten","id":"118165","full_name":"Gutmann, Torsten","last_name":"Gutmann"},{"first_name":"Gerd","full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky"}],"volume":11,"title":"Design and characterization of novel dirhodium coordination polymers – the impact of ligand size on selectivity in asymmetric cyclopropanation","doi":"10.1039/D1CY00109D"}