{"year":"2018","citation":{"apa":"Vowinkel, S., Boehm, A., Schäfer, T., Gutmann, T., Ionescu, E., &#38; Gallei, M. (2018). Preceramic core-shell particles for the preparation of hybrid colloidal crystal films by melt-shear organization and conversion into porous ceramics. <i>Materials &#38; Design</i>, <i>160</i>, 926–935. <a href=\"https://doi.org/10.1016/j.matdes.2018.10.032\">https://doi.org/10.1016/j.matdes.2018.10.032</a>","short":"S. Vowinkel, A. Boehm, T. Schäfer, T. Gutmann, E. Ionescu, M. Gallei, Materials &#38; Design 160 (2018) 926–935.","mla":"Vowinkel, Steffen, et al. “Preceramic Core-Shell Particles for the Preparation of Hybrid Colloidal Crystal Films by Melt-Shear Organization and Conversion into Porous Ceramics.” <i>Materials &#38; Design</i>, vol. 160, 2018, pp. 926–935, doi:<a href=\"https://doi.org/10.1016/j.matdes.2018.10.032\">10.1016/j.matdes.2018.10.032</a>.","bibtex":"@article{Vowinkel_Boehm_Schäfer_Gutmann_Ionescu_Gallei_2018, title={Preceramic core-shell particles for the preparation of hybrid colloidal crystal films by melt-shear organization and conversion into porous ceramics}, volume={160}, DOI={<a href=\"https://doi.org/10.1016/j.matdes.2018.10.032\">10.1016/j.matdes.2018.10.032</a>}, journal={Materials &#38; Design}, author={Vowinkel, Steffen and Boehm, Anna and Schäfer, Timmy and Gutmann, Torsten and Ionescu, Emanuel and Gallei, Markus}, year={2018}, pages={926–935} }","ama":"Vowinkel S, Boehm A, Schäfer T, Gutmann T, Ionescu E, Gallei M. Preceramic core-shell particles for the preparation of hybrid colloidal crystal films by melt-shear organization and conversion into porous ceramics. <i>Materials &#38; Design</i>. 2018;160:926–935. doi:<a href=\"https://doi.org/10.1016/j.matdes.2018.10.032\">10.1016/j.matdes.2018.10.032</a>","chicago":"Vowinkel, Steffen, Anna Boehm, Timmy Schäfer, Torsten Gutmann, Emanuel Ionescu, and Markus Gallei. “Preceramic Core-Shell Particles for the Preparation of Hybrid Colloidal Crystal Films by Melt-Shear Organization and Conversion into Porous Ceramics.” <i>Materials &#38; Design</i> 160 (2018): 926–935. <a href=\"https://doi.org/10.1016/j.matdes.2018.10.032\">https://doi.org/10.1016/j.matdes.2018.10.032</a>.","ieee":"S. Vowinkel, A. Boehm, T. Schäfer, T. Gutmann, E. Ionescu, and M. Gallei, “Preceramic core-shell particles for the preparation of hybrid colloidal crystal films by melt-shear organization and conversion into porous ceramics,” <i>Materials &#38; Design</i>, vol. 160, pp. 926–935, 2018, doi: <a href=\"https://doi.org/10.1016/j.matdes.2018.10.032\">10.1016/j.matdes.2018.10.032</a>."},"page":"926–935","intvolume":"       160","title":"Preceramic core-shell particles for the preparation of hybrid colloidal crystal films by melt-shear organization and conversion into porous ceramics","doi":"10.1016/j.matdes.2018.10.032","date_updated":"2026-02-17T16:12:52Z","date_created":"2026-02-07T16:15:42Z","author":[{"first_name":"Steffen","full_name":"Vowinkel, Steffen","last_name":"Vowinkel"},{"last_name":"Boehm","full_name":"Boehm, Anna","first_name":"Anna"},{"full_name":"Schäfer, Timmy","last_name":"Schäfer","first_name":"Timmy"},{"first_name":"Torsten","full_name":"Gutmann, Torsten","id":"118165","last_name":"Gutmann"},{"first_name":"Emanuel","full_name":"Ionescu, Emanuel","last_name":"Ionescu"},{"first_name":"Markus","full_name":"Gallei, Markus","last_name":"Gallei"}],"volume":160,"abstract":[{"lang":"eng","text":"In this work, the preparation of porous hybrid particle-based films by core-shell particle design and convenient film preparation is reported. Monodisperse core particles consisting of poly(methyl methacrylate‑co‑allyl methacrylate) (P(MMA‑co‑ALMA)) were synthesized by starved-feed emulsion polymerization followed by the introduction of an initiator-containing monomer (inimer) for subsequent atom transfer radical polymerization (ATRP). The inimer shell allowed for the introduction of allylhydrido polycarbosilane (SMP-10) under ATRP conditions by grafting to the core particles. The functionalization of the prepared core-shell particles was investigated by IR spectroscopy (FTIR), scanning transmission electron microscopy (STEM) and solid-state NMR combined with dynamic nuclear polarization (DNP). The obtained hard core/soft preceramic shell particles were subjected to the melt-shear organization technique, enabling a convenient alignment into a colloidal crystal structure in one single step without the presence of a dispersion medium or solvent for the designed particles. Moreover, the hybrid particle-based films were converted into a porous ceramic structure upon thermal treatment. As a result, freestanding ceramic porous films have been obtained after degradation of the organic template core particles. Noteworthy, the conversion of the matrix material consisting of SMP-10 into the ceramic occurred with preservation of the pristine colloidal crystal template structure. Herein, the first example of core-shell particle preparation by combining different polymerization methodologies and application of the convenient melt-shear organization technique is shown, paving a new way to ceramic materials with tailored morphology and porosity."}],"status":"public","type":"journal_article","publication":"Materials & Design","keyword":["emulsion polymerization","self-assembly","ATRP","Colloidal crystal","Hybrid film","Particle processing"],"language":[{"iso":"eng"}],"extern":"1","_id":"64054","user_id":"100715"}