{"date_updated":"2026-02-17T16:12:37Z","publisher":"The Royal Society of Chemistry","volume":12,"date_created":"2026-02-07T16:19:39Z","author":[{"last_name":"Wunder","full_name":"Wunder, Clemens","first_name":"Clemens"},{"last_name":"Lai","full_name":"Lai, Thanh-Loan","first_name":"Thanh-Loan"},{"first_name":"Edina","full_name":"Šić, Edina","last_name":"Šić"},{"last_name":"Gutmann","full_name":"Gutmann, Torsten","id":"118165","first_name":"Torsten"},{"first_name":"Eric","last_name":"Vito","full_name":"Vito, Eric"},{"first_name":"Gerd","full_name":"Buntkowsky, Gerd","last_name":"Buntkowsky"},{"last_name":"Zarrabeitia","full_name":"Zarrabeitia, Maider","first_name":"Maider"},{"first_name":"Stefano","last_name":"Passerini","full_name":"Passerini, Stefano"}],"title":"Sodium 4-styrenesulfonyl(trifluoromethanesulfonyl)imide-based single-ion conducting polymer electrolyte incorporating molecular transporters for quasi-solid-state sodium batteries","doi":"10.1039/D4TA02329C","issue":"32","year":"2024","page":"20935–20946","intvolume":"        12","citation":{"ama":"Wunder C, Lai T-L, Šić E, et al. Sodium 4-styrenesulfonyl(trifluoromethanesulfonyl)imide-based single-ion conducting polymer electrolyte incorporating molecular transporters for quasi-solid-state sodium batteries. <i>Journal of Materials Chemistry A</i>. 2024;12(32):20935–20946. doi:<a href=\"https://doi.org/10.1039/D4TA02329C\">10.1039/D4TA02329C</a>","ieee":"C. Wunder <i>et al.</i>, “Sodium 4-styrenesulfonyl(trifluoromethanesulfonyl)imide-based single-ion conducting polymer electrolyte incorporating molecular transporters for quasi-solid-state sodium batteries,” <i>Journal of Materials Chemistry A</i>, vol. 12, no. 32, pp. 20935–20946, 2024, doi: <a href=\"https://doi.org/10.1039/D4TA02329C\">10.1039/D4TA02329C</a>.","chicago":"Wunder, Clemens, Thanh-Loan Lai, Edina Šić, Torsten Gutmann, Eric Vito, Gerd Buntkowsky, Maider Zarrabeitia, and Stefano Passerini. “Sodium 4-Styrenesulfonyl(Trifluoromethanesulfonyl)Imide-Based Single-Ion Conducting Polymer Electrolyte Incorporating Molecular Transporters for Quasi-Solid-State Sodium Batteries.” <i>Journal of Materials Chemistry A</i> 12, no. 32 (2024): 20935–20946. <a href=\"https://doi.org/10.1039/D4TA02329C\">https://doi.org/10.1039/D4TA02329C</a>.","apa":"Wunder, C., Lai, T.-L., Šić, E., Gutmann, T., Vito, E., Buntkowsky, G., Zarrabeitia, M., &#38; Passerini, S. (2024). Sodium 4-styrenesulfonyl(trifluoromethanesulfonyl)imide-based single-ion conducting polymer electrolyte incorporating molecular transporters for quasi-solid-state sodium batteries. <i>Journal of Materials Chemistry A</i>, <i>12</i>(32), 20935–20946. <a href=\"https://doi.org/10.1039/D4TA02329C\">https://doi.org/10.1039/D4TA02329C</a>","bibtex":"@article{Wunder_Lai_Šić_Gutmann_Vito_Buntkowsky_Zarrabeitia_Passerini_2024, title={Sodium 4-styrenesulfonyl(trifluoromethanesulfonyl)imide-based single-ion conducting polymer electrolyte incorporating molecular transporters for quasi-solid-state sodium batteries}, volume={12}, DOI={<a href=\"https://doi.org/10.1039/D4TA02329C\">10.1039/D4TA02329C</a>}, number={32}, journal={Journal of Materials Chemistry A}, publisher={The Royal Society of Chemistry}, author={Wunder, Clemens and Lai, Thanh-Loan and Šić, Edina and Gutmann, Torsten and Vito, Eric and Buntkowsky, Gerd and Zarrabeitia, Maider and Passerini, Stefano}, year={2024}, pages={20935–20946} }","mla":"Wunder, Clemens, et al. “Sodium 4-Styrenesulfonyl(Trifluoromethanesulfonyl)Imide-Based Single-Ion Conducting Polymer Electrolyte Incorporating Molecular Transporters for Quasi-Solid-State Sodium Batteries.” <i>Journal of Materials Chemistry A</i>, vol. 12, no. 32, The Royal Society of Chemistry, 2024, pp. 20935–20946, doi:<a href=\"https://doi.org/10.1039/D4TA02329C\">10.1039/D4TA02329C</a>.","short":"C. Wunder, T.-L. Lai, E. Šić, T. Gutmann, E. Vito, G. Buntkowsky, M. Zarrabeitia, S. Passerini, Journal of Materials Chemistry A 12 (2024) 20935–20946."},"_id":"64063","user_id":"100715","language":[{"iso":"eng"}],"extern":"1","publication":"Journal of Materials Chemistry A","type":"journal_article","abstract":[{"text":"Sodium batteries are an attractive alternative for future energy storage as they can be produced with abundant and low-cost materials. Nonetheless, sodium-ion batteries (SIBs) are often composed of flammable and volatile carbonate-based liquid electrolytes. Polymer electrolytes have attracted significant attention as safer alternatives. Among polymer electrolytes, single-ion conductive polymer electrolytes (SIPEs) are considered particularly interesting because they can suppress dendrite growth, enabling high-performance (quasi)-solid-state sodium–(metal) batteries. In this work, a self-standing, flexible, quasi-solid-state SIPE is investigated, which is composed of sodium 4-styrene sulfonyl (trifluoromethanesulfonyl) imide (NaSTFSI), pentaerythritol tetrakis(3-mercaptopropionate) (PETMP) and pentaerythritol tetraacrylate (PET4A) blended with poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP). The SIPE membrane, including 50 wt% of molecular transporter, exhibits ionic conductivity of 1.4 × 10−5 S cm−1 and 1.3 × 10−4 S cm−1 at 20 °C and 90 °C, respectively, thermal stability up to 280 °C, electrochemical stability window up to 4.5 V vs. Na/Na+, and Na plating/stripping reversibility in symmetric Na‖Na cells. The manufactured SIPE implemented in Prussian White (PW)‖Na cells enables the delivery of 147 mA h g−1 of PW at 15 mA g−1 with a Coulombic efficiency of over 99%, which is comparable with the PW‖Na cells using liquid carbonate electrolyte, confirming the suitability of the designed SIPE for sodium–(metal) batteries.","lang":"eng"}],"status":"public"}