---
_id: '66419'
abstract:
- lang: eng
  text: "<jats:p>\r\n                    C\r\n                    <jats:sub>2</jats:sub>\r\n
    \                   N‐type carbon materials are typically obtained through high‐temperature
    treatment of nitrogen‐rich molecular precursors under inert atmosphere. Herein,
    we demonstrate mechanochemical approaches that enable the synthesis of C\r\n                    <jats:sub>2</jats:sub>\r\n
    \                   N materials, namely by (i) the conversion of hexaazatriphenylenehexacarbonitrile
    (HAT‐CN) and by (ii) a one‐pot route starting from its molecular precursors, hexaketocyclohexane,
    and diaminomaleonitrile. Compared with conventional pyrolytic methods, mechanochemical
    approaches afford higher yields while significantly reducing energy input, thereby
    improving overall sustainability. The results highlight the decisive role of mechanical
    energy in directing carbon–nitrogen framework formation and demonstrate mechanochemistry
    as a versatile alternative to thermal routes for C\r\n                    <jats:sub>2</jats:sub>\r\n
    \                   N synthesis.\r\n                  </jats:p>"
article_number: e70678
author:
- first_name: Pascal
  full_name: Dippner, Pascal
  last_name: Dippner
- first_name: Sven
  full_name: Grätz, Sven
  last_name: Grätz
- first_name: Jonas
  full_name: Lins, Jonas
  last_name: Lins
- first_name: Torsten
  full_name: Gutmann, Torsten
  id: '118165'
  last_name: Gutmann
- first_name: Lars
  full_name: Borchardt, Lars
  last_name: Borchardt
citation:
  ama: Dippner P, Grätz S, Lins J, Gutmann T, Borchardt L. Mechanochemical Near‐Ambient
    Synthesis of C                    <sub>2</sub>                    N Materials
    From HAT‐CN and its Precursors. <i>ChemSusChem</i>. 2026;19(9). doi:<a href="https://doi.org/10.1002/cssc.70678">10.1002/cssc.70678</a>
  apa: Dippner, P., Grätz, S., Lins, J., Gutmann, T., &#38; Borchardt, L. (2026).
    Mechanochemical Near‐Ambient Synthesis of C                    <sub>2</sub>   
                    N Materials From HAT‐CN and its Precursors. <i>ChemSusChem</i>,
    <i>19</i>(9), Article e70678. <a href="https://doi.org/10.1002/cssc.70678">https://doi.org/10.1002/cssc.70678</a>
  bibtex: '@article{Dippner_Grätz_Lins_Gutmann_Borchardt_2026, title={Mechanochemical
    Near‐Ambient Synthesis of C                    <sub>2</sub>                   
    N Materials From HAT‐CN and its Precursors}, volume={19}, DOI={<a href="https://doi.org/10.1002/cssc.70678">10.1002/cssc.70678</a>},
    number={9e70678}, journal={ChemSusChem}, publisher={Wiley}, author={Dippner, Pascal
    and Grätz, Sven and Lins, Jonas and Gutmann, Torsten and Borchardt, Lars}, year={2026}
    }'
  chicago: Dippner, Pascal, Sven Grätz, Jonas Lins, Torsten Gutmann, and Lars Borchardt.
    “Mechanochemical Near‐Ambient Synthesis of C                    <sub>2</sub> 
                      N Materials From HAT‐CN and Its Precursors.” <i>ChemSusChem</i>
    19, no. 9 (2026). <a href="https://doi.org/10.1002/cssc.70678">https://doi.org/10.1002/cssc.70678</a>.
  ieee: 'P. Dippner, S. Grätz, J. Lins, T. Gutmann, and L. Borchardt, “Mechanochemical
    Near‐Ambient Synthesis of C                    <sub>2</sub>                   
    N Materials From HAT‐CN and its Precursors,” <i>ChemSusChem</i>, vol. 19, no.
    9, Art. no. e70678, 2026, doi: <a href="https://doi.org/10.1002/cssc.70678">10.1002/cssc.70678</a>.'
  mla: Dippner, Pascal, et al. “Mechanochemical Near‐Ambient Synthesis of C       
                <sub>2</sub>                    N Materials From HAT‐CN and Its Precursors.”
    <i>ChemSusChem</i>, vol. 19, no. 9, e70678, Wiley, 2026, doi:<a href="https://doi.org/10.1002/cssc.70678">10.1002/cssc.70678</a>.
  short: P. Dippner, S. Grätz, J. Lins, T. Gutmann, L. Borchardt, ChemSusChem 19 (2026).
date_created: 2026-07-09T17:08:24Z
date_updated: 2026-07-09T17:24:31Z
doi: 10.1002/cssc.70678
intvolume: '        19'
issue: '9'
language:
- iso: eng
publication: ChemSusChem
publication_identifier:
  issn:
  - 1864-5631
  - 1864-564X
publication_status: published
publisher: Wiley
status: public
title: Mechanochemical Near‐Ambient Synthesis of C                    <sub>2</sub>                    N
  Materials From HAT‐CN and its Precursors
type: journal_article
user_id: '100715'
volume: 19
year: '2026'
...