A Damage Model for Corrosion Fatigue Due to Hydrogen Embrittlement

Predicting the durability of components subjected to mechanical load under environmental conditions leading to corrosion is one of the most challenging tasks in mechanical engineering. The demand for precise predictions increases with the desire of lightweight design in transportation due to environmental protection. Corrosion with its manifold of mechanisms often occurs together with the production of hydrogen by electrochemical reactions. Hydrogen embrittlement is one of the most feared damage mechanisms for metal constructions often leading to early and unexpected failure. Until now, predictions are mostly based on costly experiments. Hence, a rational predictive model based on the fundamentals of electrochemistry and damage mechanics has to be developed in order to reduce the costs. In this work, a first model approach based on classical continuum damage mechanics is presented to couple both, the damage induced by the mechanical stress and the hydrogen embrittlement. An elaborated two-scale model based on the selfconsistent theory is applied to describe the mechanical damage due to fatigue. The electrochemical kinetics are elucidated through the Langmuir adsorption isotherm and the diffusion equation to consider the impact of hydrogen embrittlement on the fatigue. The modeling of the mechanism of hydrogen embrittlement defines the progress of damage accumulation due to the electrochemistry. The durability results like the S-N diagram show the influence of hydrogen embrittlement by varying, e.g. the fatigue frequency or the stress ratio.