The influence of surface on direction of diffusion in Al-Fe clad material

M. Šlapáková, B. Křivská, K. Fekete, R. Králík, O. Grydin, M. Stolbchenko, M. Schaper, Materials Characterization 190 (2022).

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Journal Article | Published | English
Author
Šlapáková, Michaela; Křivská, Barbora; Fekete, Klaudia; Králík, Rostislav; Grydin, OlexandrLibreCat; Stolbchenko, Mykhailo; Schaper, MirkoLibreCat
Abstract
Aluminium-steel clad composite was manufactured by twin-roll casting. An intermetallic layer of Al5Fe2 and Al13Fe4 formed at the interface upon annealing above 500 °C. During in-situ annealing in transmission electron microscope, the layer grew towards the steel side of the interface in tongue-like protrusions. A study of furnace-annealed samples revealed, that the bulk growth of the interface phase proceeds towards the aluminium side. The growth towards steel is a surface effect that takes place simultaneously with the bulk growth towards aluminium. At the beginning of the intermetallic layer formation diffusion of Fe into aluminium prevails, afterwards Al atoms diffuse throught the newly formed intermetallic layer towards steel and the whole interface shifts towards aluminium. The kinetics of growth of the intermetallic layer follows parabolic law in both cases, indicating that the growth is governed by diffusion.
Publishing Year
Journal Title
Materials Characterization
Volume
190
Article Number
112005
ISSN
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Šlapáková M, Křivská B, Fekete K, et al. The influence of surface on direction of diffusion in Al-Fe clad material. Materials Characterization. 2022;190. doi:10.1016/j.matchar.2022.112005
Šlapáková, M., Křivská, B., Fekete, K., Králík, R., Grydin, O., Stolbchenko, M., & Schaper, M. (2022). The influence of surface on direction of diffusion in Al-Fe clad material. Materials Characterization, 190, Article 112005. https://doi.org/10.1016/j.matchar.2022.112005
@article{Šlapáková_Křivská_Fekete_Králík_Grydin_Stolbchenko_Schaper_2022, title={The influence of surface on direction of diffusion in Al-Fe clad material}, volume={190}, DOI={10.1016/j.matchar.2022.112005}, number={112005}, journal={Materials Characterization}, publisher={Elsevier BV}, author={Šlapáková, Michaela and Křivská, Barbora and Fekete, Klaudia and Králík, Rostislav and Grydin, Olexandr and Stolbchenko, Mykhailo and Schaper, Mirko}, year={2022} }
Šlapáková, Michaela, Barbora Křivská, Klaudia Fekete, Rostislav Králík, Olexandr Grydin, Mykhailo Stolbchenko, and Mirko Schaper. “The Influence of Surface on Direction of Diffusion in Al-Fe Clad Material.” Materials Characterization 190 (2022). https://doi.org/10.1016/j.matchar.2022.112005.
M. Šlapáková et al., “The influence of surface on direction of diffusion in Al-Fe clad material,” Materials Characterization, vol. 190, Art. no. 112005, 2022, doi: 10.1016/j.matchar.2022.112005.
Šlapáková, Michaela, et al. “The Influence of Surface on Direction of Diffusion in Al-Fe Clad Material.” Materials Characterization, vol. 190, 112005, Elsevier BV, 2022, doi:10.1016/j.matchar.2022.112005.

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