High cycle life all-solid-state fluoride ion battery with La2NiO4+d high voltage cathode
M.A. Nowroozi, K. Wissel, M. Donzelli, N. Hosseinpourkahvaz, S. Plana-Ruiz, U. Kolb, R. Schoch, M. Bauer, A.M. Malik, J. Rohrer, S. Ivlev, F. Kraus, O. Clemens, Communications Materials 1 (2020).
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Journal Article
| Published
| English
Author
Nowroozi, Mohammad Ali;
Wissel, Kerstin;
Donzelli, Manuel;
Hosseinpourkahvaz, Niloofar;
Plana-Ruiz, Sergi;
Kolb, Ute;
Schoch, RolandLibreCat 
;
Bauer, MatthiasLibreCat;
Malik, Ali Muhammad;
Rohrer, Jochen;
Ivlev, Sergei;
Kraus, Florian
All
;
Bauer, MatthiasLibreCat;
Malik, Ali Muhammad;
Rohrer, Jochen;
Ivlev, Sergei;
Kraus, Florian
All
Department
Abstract
<jats:title>Abstract</jats:title><jats:p>Fluoride ion batteries (FIBs) are a recent alternative all-solid-state battery technology. However, the FIB systems proposed so far suffer from poor cycling performance. In this work, we report La<jats:sub>2</jats:sub>NiO<jats:sub>4.13</jats:sub> with a Ruddlesden-Popper type structure as an intercalation-based active cathode material in all solid-state FIB with excellent cycling performance. The critical charging conditions to maintain the conductivity of the cell were determined, which seems to be a major obstacle towards improving the cycling stability of FIBs. For optimized operating conditions, a cycle life of about 60 cycles and over 220 cycles for critical cut-off capacities of 50 mAh/g and 30 mAh/g, respectively, could be achieved, with average Coulombic efficiencies between 95 – 99%. Cycling of the cell is a result of fluorination/de-fluorination into and from the La<jats:sub>2</jats:sub>NiO<jats:sub>4+d</jats:sub> cathode, and it is revealed that La<jats:sub>2</jats:sub>NiO<jats:sub>4.13</jats:sub> is a multivalent electrode material. Our findings suggest that La<jats:sub>2</jats:sub>NiO<jats:sub>4.13</jats:sub> is a promising high energy cathode for FIBs.</jats:p>
Publishing Year
Journal Title
Communications Materials
Volume
1
Issue
1
Article Number
27
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Cite this
Nowroozi MA, Wissel K, Donzelli M, et al. High cycle life all-solid-state fluoride ion battery with La<jats:sub>2</jats:sub>NiO<jats:sub>4+d</jats:sub> high voltage cathode. Communications Materials. 2020;1(1). doi:10.1038/s43246-020-0030-5
Nowroozi, M. A., Wissel, K., Donzelli, M., Hosseinpourkahvaz, N., Plana-Ruiz, S., Kolb, U., Schoch, R., Bauer, M., Malik, A. M., Rohrer, J., Ivlev, S., Kraus, F., & Clemens, O. (2020). High cycle life all-solid-state fluoride ion battery with La<jats:sub>2</jats:sub>NiO<jats:sub>4+d</jats:sub> high voltage cathode. Communications Materials, 1(1), Article 27. https://doi.org/10.1038/s43246-020-0030-5
@article{Nowroozi_Wissel_Donzelli_Hosseinpourkahvaz_Plana-Ruiz_Kolb_Schoch_Bauer_Malik_Rohrer_et al._2020, title={High cycle life all-solid-state fluoride ion battery with La<jats:sub>2</jats:sub>NiO<jats:sub>4+d</jats:sub> high voltage cathode}, volume={1}, DOI={10.1038/s43246-020-0030-5}, number={127}, journal={Communications Materials}, publisher={Springer Science and Business Media LLC}, author={Nowroozi, Mohammad Ali and Wissel, Kerstin and Donzelli, Manuel and Hosseinpourkahvaz, Niloofar and Plana-Ruiz, Sergi and Kolb, Ute and Schoch, Roland and Bauer, Matthias and Malik, Ali Muhammad and Rohrer, Jochen and et al.}, year={2020} }
Nowroozi, Mohammad Ali, Kerstin Wissel, Manuel Donzelli, Niloofar Hosseinpourkahvaz, Sergi Plana-Ruiz, Ute Kolb, Roland Schoch, et al. “High Cycle Life All-Solid-State Fluoride Ion Battery with La<jats:Sub>2</Jats:Sub>NiO<jats:Sub>4+d</Jats:Sub> High Voltage Cathode.” Communications Materials 1, no. 1 (2020). https://doi.org/10.1038/s43246-020-0030-5.
M. A. Nowroozi et al., “High cycle life all-solid-state fluoride ion battery with La<jats:sub>2</jats:sub>NiO<jats:sub>4+d</jats:sub> high voltage cathode,” Communications Materials, vol. 1, no. 1, Art. no. 27, 2020, doi: 10.1038/s43246-020-0030-5.
Nowroozi, Mohammad Ali, et al. “High Cycle Life All-Solid-State Fluoride Ion Battery with La<jats:Sub>2</Jats:Sub>NiO<jats:Sub>4+d</Jats:Sub> High Voltage Cathode.” Communications Materials, vol. 1, no. 1, 27, Springer Science and Business Media LLC, 2020, doi:10.1038/s43246-020-0030-5.
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