Insights into the First Multi-Transition-Metal Containing Ruddlesden Popper-Type Cathode for all-solid-state Fluoride Ion Batteries

V. Vanita, A.I. Waidha, S. Vasala, P. Puphal, R. Schoch, P. Glatzel, M. Bauer, O. Clemens, Journal of Materials Chemistry A (2024).

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Journal Article | Published | English
Author
Vanita, Vanita; Waidha, Aamir Iqbal; Vasala, Sami; Puphal, Pascal; Schoch, RolandLibreCat ; Glatzel, Pieter; Bauer, MatthiasLibreCat ; Clemens, Oliver
Abstract
Promising cathode materials for fluoride-ion batteries (FIBs) are 3d transition metal containing oxides with Ruddlesden-Popper-type structure. So far, multi-elemental compositions were not investigated, but could alternate electrochemical performance similar to what has been found for cathode materials for lithium-ion batteries. Within this study, we investigate RP type La2Ni0.75Co0.25O4.08 as an intercalation-based active cathode material for all-solid-state FIBs. We determine the structural changes of La2Ni0.75Co0.25O4.08 during fluoride intercalation / de-intercalation by ex-situ X-ray diffraction, which showed that F- insertion leads to transformation of the parent phase to three different phases. Changes in Ni and Co oxidation states and coordination environment were examined by X-ray absorption spectroscopy and magnetic measurements in order to understand the complex reaction behaviour of the phases in detail, showing that the two transition metals behave differently in the charging and discharging process. Under optimized operating conditions, a cycle life of 120 cycles at a critical cut-off capacity of 40 mAh g-1 against Pb/PbF2 was obtained, which is one of the highest observed for intercalation electrode materials in FIBs so far. The average Coulombic efficiencies ranged from 85% to 90%. Thus, La2Ni0.75Co0.25O4.08 could be a promising candidate for cycling-stable high-energy cathode materials for all-solid-state FIBs
Publishing Year
Journal Title
Journal of Materials Chemistry A
Issue
12
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Vanita V, Waidha AI, Vasala S, et al. Insights into the First Multi-Transition-Metal Containing Ruddlesden Popper-Type Cathode for all-solid-state Fluoride Ion Batteries. Journal of Materials Chemistry A. 2024;(12). doi:10.1039/d4ta00704b
Vanita, V., Waidha, A. I., Vasala, S., Puphal, P., Schoch, R., Glatzel, P., Bauer, M., & Clemens, O. (2024). Insights into the First Multi-Transition-Metal Containing Ruddlesden Popper-Type Cathode for all-solid-state Fluoride Ion Batteries. Journal of Materials Chemistry A, 12. https://doi.org/10.1039/d4ta00704b
@article{Vanita_Waidha_Vasala_Puphal_Schoch_Glatzel_Bauer_Clemens_2024, title={Insights into the First Multi-Transition-Metal Containing Ruddlesden Popper-Type Cathode for all-solid-state Fluoride Ion Batteries}, DOI={10.1039/d4ta00704b}, number={12}, journal={Journal of Materials Chemistry A}, publisher={Royal Society of Chemistry (RSC)}, author={Vanita, Vanita and Waidha, Aamir Iqbal and Vasala, Sami and Puphal, Pascal and Schoch, Roland and Glatzel, Pieter and Bauer, Matthias and Clemens, Oliver}, year={2024} }
Vanita, Vanita, Aamir Iqbal Waidha, Sami Vasala, Pascal Puphal, Roland Schoch, Pieter Glatzel, Matthias Bauer, and Oliver Clemens. “Insights into the First Multi-Transition-Metal Containing Ruddlesden Popper-Type Cathode for All-Solid-State Fluoride Ion Batteries.” Journal of Materials Chemistry A, no. 12 (2024). https://doi.org/10.1039/d4ta00704b.
V. Vanita et al., “Insights into the First Multi-Transition-Metal Containing Ruddlesden Popper-Type Cathode for all-solid-state Fluoride Ion Batteries,” Journal of Materials Chemistry A, no. 12, 2024, doi: 10.1039/d4ta00704b.
Vanita, Vanita, et al. “Insights into the First Multi-Transition-Metal Containing Ruddlesden Popper-Type Cathode for All-Solid-State Fluoride Ion Batteries.” Journal of Materials Chemistry A, no. 12, Royal Society of Chemistry (RSC), 2024, doi:10.1039/d4ta00704b.

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