Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide Rearrangements
L. Köring, B. Birenheide, F. Krämer, J.O. Wenzel, R. Schoch, M. Brehm, F. Breher, J. Paradies, European Journal of Inorganic Chemistry (2024).
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Journal Article
| Published
| English
Author
Köring, Laura;
Birenheide, Bernhard;
Krämer, Felix;
Wenzel, Jonas O.;
Schoch, RolandLibreCat 
;
Brehm, MartinLibreCat;
Breher, Frank;
Paradies, JanLibreCat
;
Brehm, MartinLibreCat;
Breher, Frank;
Paradies, JanLibreCat Abstract
<jats:p>A series of substituted ferrocenyl boron derivatives was synthesized. The oxidation of the ferrocenyl unit resulted in a significant increase of the boron‐centered Lewis acidity. The neutral and cationic Lewis acids were characterized by NMR‐spectroscopy, crystal structure analysis and by computational methods. The new Lewis acids were then applied in the Meinwald rearrangement of epoxides, predominantly furnishing aldehydes as the kinetic products.</jats:p>
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European Journal of Inorganic Chemistry
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Köring L, Birenheide B, Krämer F, et al. Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide Rearrangements. European Journal of Inorganic Chemistry. Published online 2024. doi:10.1002/ejic.202400057
Köring, L., Birenheide, B., Krämer, F., Wenzel, J. O., Schoch, R., Brehm, M., Breher, F., & Paradies, J. (2024). Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide Rearrangements. European Journal of Inorganic Chemistry. https://doi.org/10.1002/ejic.202400057
@article{Köring_Birenheide_Krämer_Wenzel_Schoch_Brehm_Breher_Paradies_2024, title={Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide Rearrangements}, DOI={10.1002/ejic.202400057}, journal={European Journal of Inorganic Chemistry}, publisher={Wiley}, author={Köring, Laura and Birenheide, Bernhard and Krämer, Felix and Wenzel, Jonas O. and Schoch, Roland and Brehm, Martin and Breher, Frank and Paradies, Jan}, year={2024} }
Köring, Laura, Bernhard Birenheide, Felix Krämer, Jonas O. Wenzel, Roland Schoch, Martin Brehm, Frank Breher, and Jan Paradies. “Synthesis of Ferrocenyl Boranes and Their Application as Lewis Acids in Epoxide Rearrangements.” European Journal of Inorganic Chemistry, 2024. https://doi.org/10.1002/ejic.202400057.
L. Köring et al., “Synthesis of Ferrocenyl Boranes and their Application as Lewis Acids in Epoxide Rearrangements,” European Journal of Inorganic Chemistry, 2024, doi: 10.1002/ejic.202400057.
Köring, Laura, et al. “Synthesis of Ferrocenyl Boranes and Their Application as Lewis Acids in Epoxide Rearrangements.” European Journal of Inorganic Chemistry, Wiley, 2024, doi:10.1002/ejic.202400057.
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