Synthesis, Structure and Cu-Phenylacetylide Coordination of an Unsymmetrically Substituted Bulky dppf-Analog
S. Dey, F. Roesler, M.V. Höfler, C. Bruhn, T. Gutmann, R. Pietschnig, European Journal of Inorganic Chemistry 2022 (2022) e202100939.
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Journal Article
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Author
Dey, Subhayan;
Roesler, Fabian;
Höfler, Mark V.;
Bruhn, Clemens;
Gutmann, TorstenLibreCat;
Pietschnig, Rudolf
Abstract
Abstract The donor properties of a set of bulky ferrocene based bisphosphanes (Fe(C5H4PMes2)2 and (C5H4PMes2)Fe(C5H4PtBu2 with Mes= mesityl and tBu=tert-butyl) were probed by exploring the NMR parameters of the corresponding selenophosphoranes amended by cyclovoltammetry. The ligand properties were explored in the complexation of copper phenylacetylide which is relevant as intermediate in the Cu(I) catalyzed CO2 addition to phenylacetylene. Owing to the poor solubility of the resulting complexes their characterization was performed with solid state NMR spectroscopy amended by IR spectroscopy, mass spectrometry and elemental analysis. Remarkably, these complexes feature luminescent properties, albeit with limited quantum yield.
Publishing Year
Journal Title
European Journal of Inorganic Chemistry
Volume
2022
Issue
3
Page
e202100939
LibreCat-ID
Cite this
Dey S, Roesler F, Höfler MV, Bruhn C, Gutmann T, Pietschnig R. Synthesis, Structure and Cu-Phenylacetylide Coordination of an Unsymmetrically Substituted Bulky dppf-Analog. European Journal of Inorganic Chemistry. 2022;2022(3):e202100939. doi:10.1002/ejic.202100939
Dey, S., Roesler, F., Höfler, M. V., Bruhn, C., Gutmann, T., & Pietschnig, R. (2022). Synthesis, Structure and Cu-Phenylacetylide Coordination of an Unsymmetrically Substituted Bulky dppf-Analog. European Journal of Inorganic Chemistry, 2022(3), e202100939. https://doi.org/10.1002/ejic.202100939
@article{Dey_Roesler_Höfler_Bruhn_Gutmann_Pietschnig_2022, title={Synthesis, Structure and Cu-Phenylacetylide Coordination of an Unsymmetrically Substituted Bulky dppf-Analog}, volume={2022}, DOI={10.1002/ejic.202100939}, number={3}, journal={European Journal of Inorganic Chemistry}, author={Dey, Subhayan and Roesler, Fabian and Höfler, Mark V. and Bruhn, Clemens and Gutmann, Torsten and Pietschnig, Rudolf}, year={2022}, pages={e202100939} }
Dey, Subhayan, Fabian Roesler, Mark V. Höfler, Clemens Bruhn, Torsten Gutmann, and Rudolf Pietschnig. “Synthesis, Structure and Cu-Phenylacetylide Coordination of an Unsymmetrically Substituted Bulky Dppf-Analog.” European Journal of Inorganic Chemistry 2022, no. 3 (2022): e202100939. https://doi.org/10.1002/ejic.202100939.
S. Dey, F. Roesler, M. V. Höfler, C. Bruhn, T. Gutmann, and R. Pietschnig, “Synthesis, Structure and Cu-Phenylacetylide Coordination of an Unsymmetrically Substituted Bulky dppf-Analog,” European Journal of Inorganic Chemistry, vol. 2022, no. 3, p. e202100939, 2022, doi: 10.1002/ejic.202100939.
Dey, Subhayan, et al. “Synthesis, Structure and Cu-Phenylacetylide Coordination of an Unsymmetrically Substituted Bulky Dppf-Analog.” European Journal of Inorganic Chemistry, vol. 2022, no. 3, 2022, p. e202100939, doi:10.1002/ejic.202100939.
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