At the limits of bisphosphonio-substituted stannylenes
S. Nasemann, R. Franz, D. Kargin, C. Bruhn, Z. Kelemen, T. Gutmann, R. Pietschnig, Chemistry - An Asian Journal 19 (2024) e202300950.
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Journal Article
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Author
Nasemann, Sina;
Franz, Roman;
Kargin, Denis;
Bruhn, Clemens;
Kelemen, Zsolt;
Gutmann, TorstenLibreCat;
Pietschnig, Rudolf
Abstract
Abstract Donor stabilization of Sn(II) and Pb(II) halides with 1,1?-ferrocenylene bridged bisphosphanes has been explored for Fe(C5H4P(C6H5)2)2 (dppf), and Fe(C5H4PH(C4H9))2. These bisphosphanes are reacted with SnBr2 and PbCl2 with and without additional Lewis acid (AlCl3) forming acyclic and cyclic donor adducts from which the latter represent bisphosphoniotetrylenes. Since dynamic exchange in solution is observed, characterization includes solution and solid-state NMR in addition to SC-XRD, amended by DFT calculations.
Keywords
Publishing Year
Journal Title
Chemistry - An Asian Journal
Volume
19
Issue
8
Page
e202300950
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Cite this
Nasemann S, Franz R, Kargin D, et al. At the limits of bisphosphonio-substituted stannylenes. Chemistry - An Asian Journal. 2024;19(8):e202300950. doi:10.1002/asia.202300950
Nasemann, S., Franz, R., Kargin, D., Bruhn, C., Kelemen, Z., Gutmann, T., & Pietschnig, R. (2024). At the limits of bisphosphonio-substituted stannylenes. Chemistry - An Asian Journal, 19(8), e202300950. https://doi.org/10.1002/asia.202300950
@article{Nasemann_Franz_Kargin_Bruhn_Kelemen_Gutmann_Pietschnig_2024, title={At the limits of bisphosphonio-substituted stannylenes}, volume={19}, DOI={10.1002/asia.202300950}, number={8}, journal={Chemistry - An Asian Journal}, publisher={John Wiley & Sons, Ltd}, author={Nasemann, Sina and Franz, Roman and Kargin, Denis and Bruhn, Clemens and Kelemen, Zsolt and Gutmann, Torsten and Pietschnig, Rudolf}, year={2024}, pages={e202300950} }
Nasemann, Sina, Roman Franz, Denis Kargin, Clemens Bruhn, Zsolt Kelemen, Torsten Gutmann, and Rudolf Pietschnig. “At the Limits of Bisphosphonio-Substituted Stannylenes.” Chemistry - An Asian Journal 19, no. 8 (2024): e202300950. https://doi.org/10.1002/asia.202300950.
S. Nasemann et al., “At the limits of bisphosphonio-substituted stannylenes,” Chemistry - An Asian Journal, vol. 19, no. 8, p. e202300950, 2024, doi: 10.1002/asia.202300950.
Nasemann, Sina, et al. “At the Limits of Bisphosphonio-Substituted Stannylenes.” Chemistry - An Asian Journal, vol. 19, no. 8, John Wiley & Sons, Ltd, 2024, p. e202300950, doi:10.1002/asia.202300950.
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