A solid xantphos macroligand based on porous organic polymers for the catalytic hydrogenation of CO2
A. Nisters, T. Gutmann, S.-M. Kim, J.P. Hofmann, M. Rose, RSC Sustainability 2 (2024) 2213–2217.
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Journal Article
| English
Author
Nisters, Arne;
Gutmann, TorstenLibreCat;
Kim, Sun-Myung;
Hofmann, Jan Philipp;
Rose, Marcus
Abstract
Porous organic polymers enable a novel approach to incorporate xantphos into a solid macroligand. Immobilizing a ruthenium complex on the xantphos framework results in an excellent catalyst for the hydrogenation of CO2 to formic acid. Recycling experiments indicate a minor partial degradation of the heterogenous catalyst after a certain induction period, which is referred to its structural changes.
Publishing Year
Journal Title
RSC Sustainability
Volume
2
Issue
8
Page
2213–2217
LibreCat-ID
Cite this
Nisters A, Gutmann T, Kim S-M, Hofmann JP, Rose M. A solid xantphos macroligand based on porous organic polymers for the catalytic hydrogenation of CO2. RSC Sustainability. 2024;2(8):2213–2217. doi:10.1039/D4SU00164H
Nisters, A., Gutmann, T., Kim, S.-M., Hofmann, J. P., & Rose, M. (2024). A solid xantphos macroligand based on porous organic polymers for the catalytic hydrogenation of CO2. RSC Sustainability, 2(8), 2213–2217. https://doi.org/10.1039/D4SU00164H
@article{Nisters_Gutmann_Kim_Hofmann_Rose_2024, title={A solid xantphos macroligand based on porous organic polymers for the catalytic hydrogenation of CO2}, volume={2}, DOI={10.1039/D4SU00164H}, number={8}, journal={RSC Sustainability}, publisher={RSC}, author={Nisters, Arne and Gutmann, Torsten and Kim, Sun-Myung and Hofmann, Jan Philipp and Rose, Marcus}, year={2024}, pages={2213–2217} }
Nisters, Arne, Torsten Gutmann, Sun-Myung Kim, Jan Philipp Hofmann, and Marcus Rose. “A Solid Xantphos Macroligand Based on Porous Organic Polymers for the Catalytic Hydrogenation of CO2.” RSC Sustainability 2, no. 8 (2024): 2213–2217. https://doi.org/10.1039/D4SU00164H.
A. Nisters, T. Gutmann, S.-M. Kim, J. P. Hofmann, and M. Rose, “A solid xantphos macroligand based on porous organic polymers for the catalytic hydrogenation of CO2,” RSC Sustainability, vol. 2, no. 8, pp. 2213–2217, 2024, doi: 10.1039/D4SU00164H.
Nisters, Arne, et al. “A Solid Xantphos Macroligand Based on Porous Organic Polymers for the Catalytic Hydrogenation of CO2.” RSC Sustainability, vol. 2, no. 8, RSC, 2024, pp. 2213–2217, doi:10.1039/D4SU00164H.
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