Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids
P. Hou, S. Peschtrich, W. Feuerstein, R. Schoch, S. Hohloch, F. Breher, J. Paradies, ChemistryOpen 12 (2023).
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Journal Article
| Published
| English
Author
Hou, Peng;
Peschtrich, Sebastian;
Feuerstein, Wolfram;
Schoch, Roland;
Hohloch, Stephan;
Breher, Frank;
Paradies, JanLibreCat 
Abstract
<jats:title>Abstract</jats:title><jats:p>The synthesis of three novel imidazolyl‐substituted sulfur‐containing heteroacenes is reported. These heteroacenes consisting of annelated benzo‐ and naphthothiophenes serve as precursors for the generation of open‐shell quinoid heteroacenes by oxidation with alkaline ferric cyanide. Spectroscopic and computational experiments support the formation of reactive open‐shell quinoids, which, however, quickly produce paramagnetic polymeric material.</jats:p>
Publishing Year
Journal Title
ChemistryOpen
Volume
12
Issue
11
Article Number
e202300003
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Cite this
Hou P, Peschtrich S, Feuerstein W, et al. Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids. ChemistryOpen. 2023;12(11). doi:10.1002/open.202300003
Hou, P., Peschtrich, S., Feuerstein, W., Schoch, R., Hohloch, S., Breher, F., & Paradies, J. (2023). Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids. ChemistryOpen, 12(11), Article e202300003. https://doi.org/10.1002/open.202300003
@article{Hou_Peschtrich_Feuerstein_Schoch_Hohloch_Breher_Paradies_2023, title={Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids}, volume={12}, DOI={10.1002/open.202300003}, number={11e202300003}, journal={ChemistryOpen}, publisher={Wiley}, author={Hou, Peng and Peschtrich, Sebastian and Feuerstein, Wolfram and Schoch, Roland and Hohloch, Stephan and Breher, Frank and Paradies, Jan}, year={2023} }
Hou, Peng, Sebastian Peschtrich, Wolfram Feuerstein, Roland Schoch, Stephan Hohloch, Frank Breher, and Jan Paradies. “Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids.” ChemistryOpen 12, no. 11 (2023). https://doi.org/10.1002/open.202300003.
P. Hou et al., “Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids,” ChemistryOpen, vol. 12, no. 11, Art. no. e202300003, 2023, doi: 10.1002/open.202300003.
Hou, Peng, et al. “Imidazolyl‐Substituted Benzo‐ and Naphthodithiophenes as Precursors for the Synthesis of Transient Open‐Shell Quinoids.” ChemistryOpen, vol. 12, no. 11, e202300003, Wiley, 2023, doi:10.1002/open.202300003.
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