Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds

A. Hoppe, A.J. Stepen, L. Köring, J. Paradies, Advanced Synthesis & Catalysis 366 (2024) 2933–2938.

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Journal Article | Published | English
Author
Hoppe, Axel; Stepen, Arne J.; Köring, Laura; Paradies, JanLibreCat
Abstract
<jats:title>Abstract</jats:title><jats:p>The activation of C(<jats:italic>sp</jats:italic><jats:sup>3</jats:sup>)−F bonds by the commercially available catalyst B(C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub>)<jats:sub>3</jats:sub> is reported and applied in reactions with arenes, allylic, vinylic and acetylenic silanes, and olefins to achieve a variety of C−C bond formations (45 examples).</jats:p>
Publishing Year
Journal Title
Advanced Synthesis & Catalysis
Volume
366
Issue
13
Page
2933-2938
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Hoppe A, Stepen AJ, Köring L, Paradies J. Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds. Advanced Synthesis &amp; Catalysis. 2024;366(13):2933-2938. doi:10.1002/adsc.202400511
Hoppe, A., Stepen, A. J., Köring, L., & Paradies, J. (2024). Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds. Advanced Synthesis &amp; Catalysis, 366(13), 2933–2938. https://doi.org/10.1002/adsc.202400511
@article{Hoppe_Stepen_Köring_Paradies_2024, title={Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds}, volume={366}, DOI={10.1002/adsc.202400511}, number={13}, journal={Advanced Synthesis &amp; Catalysis}, publisher={Wiley}, author={Hoppe, Axel and Stepen, Arne J. and Köring, Laura and Paradies, Jan}, year={2024}, pages={2933–2938} }
Hoppe, Axel, Arne J. Stepen, Laura Köring, and Jan Paradies. “Tris(Pentafluorophenyl)Borane‐Catalyzed Functionalization of Benzylic C−F Bonds.” Advanced Synthesis &amp; Catalysis 366, no. 13 (2024): 2933–38. https://doi.org/10.1002/adsc.202400511.
A. Hoppe, A. J. Stepen, L. Köring, and J. Paradies, “Tris(pentafluorophenyl)borane‐Catalyzed Functionalization of Benzylic C−F Bonds,” Advanced Synthesis &amp; Catalysis, vol. 366, no. 13, pp. 2933–2938, 2024, doi: 10.1002/adsc.202400511.
Hoppe, Axel, et al. “Tris(Pentafluorophenyl)Borane‐Catalyzed Functionalization of Benzylic C−F Bonds.” Advanced Synthesis &amp; Catalysis, vol. 366, no. 13, Wiley, 2024, pp. 2933–38, doi:10.1002/adsc.202400511.

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