Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis
M. Kirchhof, K. Gugeler, A.-K. Beurer, F.R. Fischer, D. Batman, S.M. Bauch, S. Kolin, E. Nicholas, R. Schoch, C. Vogler, S.R. Kousik, A. Zens, B. Plietker, P. Atanasova, S. Naumann, M. Bauer, J.R. Bruckner, Y. Traa, J. Kästner, S. Laschat, Catalysis Science Technology 13 (2023) 3709–3724.
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Journal Article
| Published
| English
Author
Kirchhof, Manuel;
Gugeler, Katrin;
Beurer, Ann-Katrin;
Fischer, Felix Richard;
Batman, Derman;
Bauch, Soeren M.;
Kolin, Sofia;
Nicholas, Elliot;
Schoch, RolandLibreCat 
;
Vogler, Charlotte;
Kousik, Shravan R.;
Zens, Anna
All
;
Vogler, Charlotte;
Kousik, Shravan R.;
Zens, Anna
All
Department
Abstract
Improved enantioselectivity in the 1,2-addition was observed for chiral Rh norbornadiene catalysts immobilized on ordered mesoporous silica with small pores. Confinement effects were rationalized by experimental and computational studies.
Keywords
Publishing Year
Journal Title
Catalysis Science Technology
Volume
13
Issue
12
Page
3709-3724
LibreCat-ID
Cite this
Kirchhof M, Gugeler K, Beurer A-K, et al. Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis. Catalysis Science Technology. 2023;13(12):3709-3724. doi:10.1039/d3cy00381g
Kirchhof, M., Gugeler, K., Beurer, A.-K., Fischer, F. R., Batman, D., Bauch, S. M., Kolin, S., Nicholas, E., Schoch, R., Vogler, C., Kousik, S. R., Zens, A., Plietker, B., Atanasova, P., Naumann, S., Bauer, M., Bruckner, J. R., Traa, Y., Kästner, J., & Laschat, S. (2023). Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis. Catalysis Science Technology, 13(12), 3709–3724. https://doi.org/10.1039/d3cy00381g
@article{Kirchhof_Gugeler_Beurer_Fischer_Batman_Bauch_Kolin_Nicholas_Schoch_Vogler_et al._2023, title={Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis}, volume={13}, DOI={10.1039/d3cy00381g}, number={12}, journal={Catalysis Science Technology}, publisher={Royal Society of Chemistry (RSC)}, author={Kirchhof, Manuel and Gugeler, Katrin and Beurer, Ann-Katrin and Fischer, Felix Richard and Batman, Derman and Bauch, Soeren M. and Kolin, Sofia and Nicholas, Elliot and Schoch, Roland and Vogler, Charlotte and et al.}, year={2023}, pages={3709–3724} }
Kirchhof, Manuel, Katrin Gugeler, Ann-Katrin Beurer, Felix Richard Fischer, Derman Batman, Soeren M. Bauch, Sofia Kolin, et al. “Tethering Chiral Rh Diene Complexes inside Mesoporous Solids: Experimental and Theoretical Study of Substituent, Pore and Linker Effects on Asymmetric Catalysis.” Catalysis Science Technology 13, no. 12 (2023): 3709–24. https://doi.org/10.1039/d3cy00381g.
M. Kirchhof et al., “Tethering chiral Rh diene complexes inside mesoporous solids: experimental and theoretical study of substituent, pore and linker effects on asymmetric catalysis,” Catalysis Science Technology, vol. 13, no. 12, pp. 3709–3724, 2023, doi: 10.1039/d3cy00381g.
Kirchhof, Manuel, et al. “Tethering Chiral Rh Diene Complexes inside Mesoporous Solids: Experimental and Theoretical Study of Substituent, Pore and Linker Effects on Asymmetric Catalysis.” Catalysis Science Technology, vol. 13, no. 12, Royal Society of Chemistry (RSC), 2023, pp. 3709–24, doi:10.1039/d3cy00381g.
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