A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes
S. Peschtrich, R. Schoch, D. Kuckling, J. Paradies, European Journal of Organic Chemistry 27 (2024).
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<jats:title>Abstract</jats:title><jats:p>We conducted an investigation into the palladium‐catalyzed carbon‐sulfur cross‐coupling reaction involving a 2‐bromothiophene derivative and potassium thioacetate as a substitute for hydrogen sulfide. This investigation utilized kinetic and computational methods. We synthesized two palladium complexes supported by the bisphosphane ligands bis(diphenylphosphino)ferrocene (DPPF) and bis(diisopropylphosphino)ferrocene (D<jats:italic>i</jats:italic>PPF), as well as their tentative intermediates in the catalytic cycle. Reaction rates were measured and then compared to computational predictions.</jats:p>
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European Journal of Organic Chemistry
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27
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8
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Peschtrich S, Schoch R, Kuckling D, Paradies J. A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes. European Journal of Organic Chemistry. 2024;27(8). doi:10.1002/ejoc.202301207
Peschtrich, S., Schoch, R., Kuckling, D., & Paradies, J. (2024). A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes. European Journal of Organic Chemistry, 27(8). https://doi.org/10.1002/ejoc.202301207
@article{Peschtrich_Schoch_Kuckling_Paradies_2024, title={A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes}, volume={27}, DOI={10.1002/ejoc.202301207}, number={8}, journal={European Journal of Organic Chemistry}, publisher={Wiley}, author={Peschtrich, Sebastian and Schoch, Roland and Kuckling, Dirk and Paradies, Jan}, year={2024} }
Peschtrich, Sebastian, Roland Schoch, Dirk Kuckling, and Jan Paradies. “A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes.” European Journal of Organic Chemistry 27, no. 8 (2024). https://doi.org/10.1002/ejoc.202301207.
S. Peschtrich, R. Schoch, D. Kuckling, and J. Paradies, “A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes,” European Journal of Organic Chemistry, vol. 27, no. 8, 2024, doi: 10.1002/ejoc.202301207.
Peschtrich, Sebastian, et al. “A Comparative Kinetic and Computational Investigation of the Carbon‐Sulfur Cross Coupling of Potassium Thioacetate and 2‐Bromo Thiophene Using Palladium/Bisphosphine Complexes.” European Journal of Organic Chemistry, vol. 27, no. 8, Wiley, 2024, doi:10.1002/ejoc.202301207.
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